Microcalorimetric in situ synthesis and the solid-state reaction enthalpy change for 1D CoII coordination polymer

Author(s):  
Yixia Ren ◽  
Xue Yang ◽  
Zhixiang Wang ◽  
Yue Wu ◽  
Xunpeng Xu ◽  
...  
2016 ◽  
Vol 42 (2) ◽  
pp. 3411-3417 ◽  
Author(s):  
Zhi-jie Liu ◽  
Wen-chun Wang ◽  
De-zheng Yang ◽  
Sen Wang ◽  
Le-yang Dai ◽  
...  

2019 ◽  
Vol 7 (9) ◽  
pp. 4660-4667 ◽  
Author(s):  
Qiao Hu ◽  
Jia-Ying Liao ◽  
Xiao-Dong He ◽  
Shuo Wang ◽  
Li-Na Xiao ◽  
...  

A series of Na3V2−xGax(PO4)3 (x = 0, 0.1, 0.2, 0.4 and 0.6) with in situ catalytic formation of graphene-like graphitic layer decoration are synthesized via a solid-state reaction process.


2020 ◽  
Vol 62 (4) ◽  
pp. 621
Author(s):  
Р.Р. Алтунин ◽  
Е.Т. Моисеенко ◽  
С.М. Жарков

Based on the study of a solid-state reaction process in Al/Ag thin films (the atomic ratio being Al:Ag=1:3) carried out by in situ electron diffraction method and electrical resistivity measurements, the reaction initiation temperature has been determined and a model of structural phase transitions occurring during the solid-state reaction has been proposed. The solid-state reaction begins at 70°C with the formation of an Al-Ag solid solution at the interface of aluminum and silver nanolayers. It has been found that in the reaction process intermetallic compounds γ-Ag2Al => µ-Ag3Al are successively formed. It has been established that for the formation of the µ-Ag3Al phase in thin films (up to 100 nm) the following is necessary: first, significant excess of silver over aluminum in the atomic composition, second, the formation of the µ-Ag3Al phase begins only after all the FCC aluminum has reacted. The work was supported by the Russian Science Foundation (grant #18-13-00080).


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