Review of Man-Made and Secondary Raw Materials of Platinum-Group Metals and their Classification

Metallurgist ◽  
2021 ◽  
Author(s):  
S. A. Fedorov ◽  
A. M. Amdur
Author(s):  
Giovanna Nicol ◽  
Emma Goosey ◽  
Deniz Şanlı Yıldız ◽  
Elaine Loving ◽  
Viet Tu Nguyen ◽  
...  

PLATInum group metals Recovery Using Secondary raw materials (PLATIRUS), a European Union (EU) Horizon 2020 project, aims to address the platinum group metal (pgm) supply security within Europe by developing novel and greener pgm recycling processes for autocatalysts, mining and electronic wastes. The initial focus was on laboratory-scale research into ionometallurgical leaching, microwave assisted leaching, solvometallurgical leaching, liquid separation, solid phase separation, electrodeposition, electrochemical process: gas-diffusion electrocrystallisation and selective chlorination. These technologies were evaluated against key performance indicators (KPIs) including recovery, environmental impact and process compatibility; with the highest scoring technologies combining to give the selected PLATIRUS flowsheet comprising microwave assisted leaching, non-conventional liquid-liquid extraction and gas-diffusion electrocrystallisation. Operating in cascade, the PLATIRUS flowsheet processed ~1.3 kg of spent milled autocatalyst and produced 1.2 g palladium, 0.8 g platinum and 0.1 g rhodium in nitrate form with a 92–99% purity. The overall recoveries from feedstock to product were calculated as 46 ± 10%, 32 ± 8% and 27 ± 3% for palladium, platinum and rhodium respectively. The recycled pgm has been manufactured into autocatalysts for validation by end users. This paper aims to be a project overview, an in‐depth technical analysis into each technology is not included. It summarises the most promising technologies explored, the technology evaluation, operation of the selected technologies in cascade, the planned recycled pgm end user validation and the next steps required to ready the technologies for implementation and to further validate their potential.


2020 ◽  
Vol 244 ◽  
pp. 462-473
Author(s):  
Tatyana Aleksandrova ◽  
Cyril О’Connor

The presented study is devoted to a comparative review of the mineral raw material base of platinum group metals (PGMs) and technologies of their processing in South Africa and Russia, the largest PGM producers. Mineralogical and geochemical classification and industrial value of iron-platinum and platinum-bearing deposits are presented in this work. The paper also reviews types of PGM ore body occurrences, ore processing methods (with a special focus on flotation processes), as well as difficulties encountered by enterprises at the processing stage, as they increase recovery of the valuable components. Data on mineralogical features of PGM deposits, including the distribution of elements in the ores, are provided. The main lines of research on mineralogical features and processing of raw materials of various genesis are identified and validated.  Sulfide deposits are found to be of the highest industrial value in both countries. Such unconventional PGM sources, as black shale, dunites, chromite, low-sulfide, chromium and titanomagnetite ores, anthropogenic raw materials, etc. are considered. The main lines of research that would bring into processing non-conventional metal sources are substantiated. Analysis of new processing and metallurgical methods of PGM recovery from non-conventional and industrial raw materials is conducted; the review of existing processing technologies for platinum-bearing raw materials is carried out. Technologies that utilize modern equipment for ultrafine grinding are considered, as well as existing reagents for flotation recovery; evaluation of their selectivity in relation to platinum minerals is presented. Basing on the analysis of main technological processes of PGM ore treatment, the most efficient schemes are identified, i.e.,gravity and flotation treatment with subsequent metallurgical processing.


2018 ◽  
Vol 3 (5) ◽  
pp. 154
Author(s):  
E A Devyatykh ◽  
T O Devyatykh ◽  
A N Boyarsky

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2021 ◽  
Vol 133 (18) ◽  
pp. 10472-10480
Author(s):  
Jiawei Zhu ◽  
Lang Xu ◽  
Zhiheng Lyu ◽  
Minghao Xie ◽  
Ruhui Chen ◽  
...  

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