Synthesis, X-ray crystal structure, electrochemical and antibacterial activity of a silver(I) complex with α-bromo-cinnamaldehyde salicylhydrazone

Two new bis-Schiff bases containing a piperazine ring, N,N‘-bis(4-chlorobenzylidene)- and N,N‘-bis(4-cyanobenzylidene)-1,4-bis(3-aminopropyl)piperazine, were prepared by the reaction of N,N‘-bis(3-aminopropyl)piperazine with 4-chloro- and 4-cyanobenzaldehyde, respectively. The dichloro compound was fully identified by X-ray crystallography and it exhibited good antibacterial activity against Escherichia coli, Staphylococcus aureus and Bacillus subtilis.

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Synthesis, Crystal Structure and Antibacterial Activity of 1D Chain Ca(II) Coordination Polymer

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.282-283.96 ◽

2011 ◽

Vol 282-283 ◽

pp. 96-99

Author(s):

Xi Shi Tai

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

Coordination Polymer ◽

Chain Structure ◽

Molar Conductance ◽

Dimensional Chain ◽

X Ray Diffraction ◽

One Dimensional ◽

X Ray ◽

1D Chain

1D chain Ca(II) coordination polymer was synthesized and characterized by elemental analysis, molar conductance, IR and single-crystal X-ray diffraction, The results of crystal structure show that each Ca(II) ion forms eight-coordinated and the complex formed one dimensional chain structure by the oxygen atoms of carboxylate and water bridged. The antibacterial activity of the Ca(II) coordination polymer and the ligand were tested, the results show that the complex show considerable antibacterial activity against escherichia coli, bacillus subtilis and staphylococcus white.

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Metallocenyl 7‐ACA Conjugates: Antibacterial Activity Studies and Atomic‐Resolution X‐ray Crystal Structure with CTX‐M β‐Lactamase

ChemBioChem ◽

10.1002/cbic.202000054 ◽

2020 ◽

Vol 21 (15) ◽

pp. 2187-2195

Author(s):

Eric M. Lewandowski ◽

Łukasz Szczupak ◽

Aleksandra Kowalczyk ◽

Gracia Mendoza ◽

Manuel Arruebo ◽

...

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

Atomic Resolution ◽

X Ray

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Corrigendum to

Journal of Molecular Structure ◽

10.1016/j.molstruc.2022.132424 ◽

2022 ◽

pp. 132424

Author(s):

Amel Marir ◽

Toma Nardjes Mouas ◽

Barkahem Anak ◽

Erwann Jeanneau ◽

Amel Djedouani ◽

...

Keyword(s):

Molecular Structure ◽

Crystal Structure ◽

Antibacterial Activity ◽

Computational Studies ◽

X Ray

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X-ray crystal structure of a Cu(II) complex with the antiparasitic drug tinidazole, interaction with calf thymus DNA and evidence for antibacterial activity

Journal of Coordination Chemistry ◽

10.1080/00958972.2013.879647 ◽

2014 ◽

Vol 67 (2) ◽

pp. 265-285 ◽

Cited By ~ 27

Author(s):

Ramesh Chandra Santra ◽

Kushal Sengupta ◽

Rajdip Dey ◽

Tahsina Shireen ◽

Piyal Das ◽

...

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

Calf Thymus Dna ◽

X Ray ◽

Antiparasitic Drug ◽

Calf Thymus

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Fabrication of Poly(Butylene Succinate) Composite Films with Silver Doped ZSM-5: Effect of Silver ZSM-5 on Antibacterial Activity and Biodegradable Behavior

Materials Science Forum ◽

10.4028/www.scientific.net/msf.990.256 ◽

2020 ◽

Vol 990 ◽

pp. 256-261

Author(s):

Nissapa Wattanawong ◽

Kanchana Chatchaipaiboon ◽

Natchanan Sreekirin ◽

Duangdao Aht-Ong

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

High Efficiency ◽

Composite Films ◽

Filler Concentration ◽

Butylene Succinate ◽

Soil Burial Test ◽

X Ray ◽

Soil Burial ◽

Silver Zeolite

This work was focused on the effects of filler concentration on the antibacterial activity and biodegradable behavior of poly (butylene succinate) (PBS) composite films containing silver exchanged zeolite ZSM-5 (SZSM-5). The composite films were prepared by chill roll cast film extrusion, by varying the silver zeolite content from 0.5 to 4 %wt. The silver content in zeolite was examined by energy dispersive X-ray spectroscopy (EDX). The morphology and crystal structure of silver zeolite were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) technique, respectively. The incorporation of silver did not influence the zeolite morphology and its crystal structure. The antibacterial action of composite films was investigated against gram-negative Escherichia coli and gram-positive Staphylococcus aureus. The results revealed that the PBS composite films containing SZSM-5 showed 99.9% of bacterial reduction. The optimal SZSM-5 content in PBS composite films was 0.5%wt because it was the lowest concentration that showed high efficiency of antibacterial behavior. In case of biodegradable ability, PBS composite films incorporated with 0.5%wt of SZSM-5 exhibited the degradation after three-month of soil burial test, although they exhibited slower rate than neat PBS films. The SEM micrographs of the films after soil burial test displayed the cavity on film surface, indicating the biodegradable properties of the films. PBS composite films incorporated with 0.5%wt of SZSM-5 showed the potential to be used as the food packaging.

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Synthesis,Crystal Structure and Antibacterial Activity of Nickel Complex with 5-Bromo-2- Hydroxyphenyl Ethyl Ketone Benzoyl Hydrazone

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.239-242.2153 ◽

2011 ◽

Vol 239-242 ◽

pp. 2153-2157 ◽

Cited By ~ 1

Author(s):

Chang Zheng Zheng ◽

Liang Wang ◽

Juan Liu

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

Nickel Chloride ◽

Nickel Atom ◽

Title Complex ◽

X Ray Diffraction ◽

Pyridine Ligand ◽

Monoclinic System ◽

X Ray ◽

Benzoyl Hydrazone

The title complex, [(C5H5N)Ni(C15H11N2O2Br)], was synthesized by the reaction of the 5-bromo-2-hydroxyphenyl ethyl ketone benzoyl hydrazone, pyridine ligand and nickel chloride in acetone. The crystal structure was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group C2/c with a = 29.507(4) Ǻ, b = 7.7738(11) Ǻ, c = 20.205(3) Ǻ, β = 126.614(2)º, Z = 8, V = 3720.1(9) Ǻ3. Its crystal structure was determined and refined to a final R= 0.0304 for 8902 independent reflections. The center nickel atom is four-coordinated. The antibacterial activity of the ligand and its complex was also studied.The antibacterial experiments indicate that they have antibacterial activity to P.aeruginosa, S.aureus, E.coli and the complex has higher activity than the ligand.

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Synthesis, characterization, X-ray crystal structure and antibacterial activity of nickel, palladium and platinum complexes with Schiff base derived from N-cyclohexylhydrazinecarbothioamide and 5-(tert-butyl)-2-hydroxybenzaldehyde

Phosphorus Sulfur and Silicon and the Related Elements ◽

10.1080/10426507.2020.1871344 ◽

2021 ◽

pp. 1-8

Author(s):

Md. Azharul Arafath ◽

Farook Adam ◽

Mohd. Zaheen Hassan

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

Schiff Base ◽

Platinum Complexes ◽

X Ray ◽

Tert Butyl ◽

Palladium And Platinum Complexes

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Synthesis, Spectroscopic Characterization and Antibacterial Activity of Organotin(IV) Complexes Containing Hydrazone Ligand: X-ray Single Crystal Structure of [n-Bu2Sn(H2PAI).H2O]

Journal of Scientific Research ◽

10.3329/jsr.v1i2.1775 ◽

2009 ◽

Vol 1 (2) ◽

pp. 306-316 ◽

Cited By ~ 6

Author(s):

M. A. Affan ◽

B. A. Fasihuddin ◽

Y. Z. Liew ◽

S. W. Foo ◽

J. Ismail

Keyword(s):

Crystal Structure ◽

Antibacterial Activity ◽

Pyruvic Acid ◽

Chelating Agent ◽

Antimicrobial Activities ◽

Absolute Methanol ◽

Spectral Studies ◽

Distorted Octahedral Geometry ◽

Hydrazone Ligand ◽

X Ray

Five new organotin(IV) complexes with pyruvic acid isonicotinoyl hydrazone [H4PAI (1)] of the general formula [Me2Sn(H2PAI)] (2), [R2Sn(H2PAI).H2O] [R=n-Bu, (3) or Ph, (4)], [RSnCl(H2PAI).H2O] [R=Me (5) or Ph (6)] have been synthesized in the presence of base in absolute methanol in 1:2:1 mole ratio (metal:base:ligand). All organotin(IV) complexes are characterized by elemental analyses, molar conductance values, UV-Visible, IR and 1H NMR spectral studies. The crystal structure of organotin(IV) complex (3) has also been determined by X-ray crystallography diffraction analyses. Complex [n-Bu2Sn(H2PAI).H2O] (3) is orthorhombic with space group P2(1)/c with a=27.517(5), b=9.6574(18), c=15.742(3) Å, α=90°, β=90°, γ=90°, V=4183.4(13) Å3, Z=8 and Dcalc=1.448 mg m-3. The complex [n-Bu2Sn(H2PAI).H2O] (3) shows a distorted octahedral geometry with coordination for the central tin(IV) atom and exhibits two monomeric structures in one unit cell. In the complex (3), the pyruvic acid isonicotinoyl hydrazone ligand is coordinated to the tin(IV) as dinegative tridentate chelating agent via the carboxylic-O, enolic-O and imine-N atoms. Hydrazone ligand (1) and its organotin(IV) complexes have also been screened for their antimicrobial activities and found to be relatively active.Keywords: Organotin(IV) complexes; Hydrazone ligand; Spectral studies; Crystal structure; Antibacterial activity.© 2009 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.DOI: 10.3329/jsr.v1i2.1775

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