A ceramic coating grows on the surface of Q235 carton steel in situ by the micro-arc oxidation method and the silicate electrolyte system; and the phase composition, surface topography and elementary composition of the ceramic coating are analyzed by X-ray diffractometer (XRD), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (EDS). The results show that the ceramic coating growing on the surface of Q235 carton steel in situ presents an irregular porous structure; and the electrolyte and the element in the basal body exist in the ceramic coating in the form of amorphous state. And then, the author degrades the rhodamine B solution by the home-made ceramic coating and H2O2Fenton system, so that the degradation rate of the rhodamine B solution can reach 97%; and meanwhile, the degradation rate is not reduced along the increased using times.