N-phosphoryl amino acid models for P-N bonds in prebiotic chemical evolution

2015 ◽  
Vol 58 (3) ◽  
pp. 374-382 ◽  
Author(s):  
Feng Ni ◽  
Chuan Fu ◽  
Xiang Gao ◽  
Yan Liu ◽  
Pengxiang Xu ◽  
...  
Keyword(s):  
Amino Acid ◽  
Chemical Evolution ◽  
Prebiotic Chemical

Histidine Self-assembly and Stability on Mineral Surfaces as a Model of Prebiotic Chemical Evolution: An Experimental and Computational Approach

2021 ◽  
Author(s):  
D. Madrigal-Trejo ◽  
P.S. Villanueva-Barragán ◽  
R. Zamudio-Ramírez ◽  
K. E. Cervantes-de la Cruz ◽  
I. Mejía-Luna ◽  
...  
Keyword(s):  
Chemical Evolution ◽  
Self Assembly ◽  
Computational Approach ◽  
Mineral Surfaces ◽  
Prebiotic Chemical

Primordial Radioactivity and Prebiotic Chemical Evolution: Effect of γ Radiation on Formamide-Based Synthesis

2020 ◽  
Vol 124 (41) ◽  
pp. 8951-8959
Author(s):  
Adam Pastorek ◽  
Martin Ferus ◽  
Václav Čuba ◽  
Ondřej Šrámek ◽  
Ondřej Ivanek ◽  
...  
Keyword(s):  
Chemical Evolution ◽  
Γ Radiation ◽  
Prebiotic Chemical ◽  
Evolution Effect

Organic matter in carbonaceous meteorites: past, present and future research

2005 ◽  
Vol 363 (1837) ◽  
pp. 2729-2742 ◽  
Author(s):  
Mark A Sephton
Keyword(s):  
Organic Matter ◽  
Solar System ◽  
Chemical Evolution ◽  
Chemical Environment ◽  
Future Research ◽  
Organic Chemical ◽  
Early Solar System ◽  
Organic Mixtures ◽  
Prebiotic Chemical ◽  
Life On Earth

Carbonaceous meteorites are fragments of ancient asteroids that have remained relatively unprocessed since the formation of the Solar System. These carbon-rich objects provide a record of prebiotic chemical evolution and a window on the early Solar System. Many compound classes are present reflecting a rich organic chemical environment during the formation of the planets. Recent theories suggest that similar extraterrestrial organic mixtures may have acted as the starting materials for life on Earth.

scholarly journals Chemical evolution of amino acid induced by soft X-ray with synchrotron radiation

2005 ◽  
Vol 144-147 ◽  
pp. 291-294 ◽  
Author(s):  
F. Kaneko ◽  
M. Tanaka ◽  
S. Narita ◽  
T. Kitada ◽  
T. Matsui ◽  
...  
Keyword(s):  
Amino Acid ◽  
Synchrotron Radiation ◽  
Chemical Evolution ◽  
X Ray

scholarly journals Defects on a pyrite(100) surface produce chemical evolution of glycine under inert conditions: experimental and theoretical approaches

2019 ◽  
Vol 21 (44) ◽  
pp. 24535-24542 ◽  
Author(s):  
Santos Galvez-Martinez ◽  
Elizabeth Escamilla-Roa ◽  
Maria-Paz Zorzano ◽  
Eva Mateo-Marti
Keyword(s):  
Amino Acid ◽  
Chemical Evolution ◽  
Theoretical Approaches ◽  
Suitable Substrate ◽  
Over Time ◽  
Amino Acid Glycine

The presence of non-stoichiometric sites on the pyrite(100) surface makes it a suitable substrate for driving the chemical evolution of the amino acid glycine over time, even under inert conditions.

Prebiotic chemical evolution: a meteoritic perspective

2011 ◽  
Vol 22 (2) ◽  
pp. 153-163 ◽  
Author(s):  
Sandra Pizzarello
Keyword(s):  
Chemical Evolution ◽  
Prebiotic Chemical

scholarly journals Complex molecular mixtures under cycling gradients as basis for life’s origins

2016 ◽  
Author(s):  
Jan Spitzer ◽  
Bert Poolman
Keyword(s):  
Molecular Recognition ◽  
Chemical Evolution ◽  
Second Law Of Thermodynamics ◽  
Physicochemical Process ◽  
Darwinian Evolution ◽  
Cellular Organization ◽  
Prebiotic Chemical ◽  
Molecular Mixtures ◽  
Molecular Complexity ◽  
Molecular Forces

AbstractWe consider life as a cyclic physicochemical process that makes heredity and Darwinian evolution observable through living cells. We elaborate four principles that constrain current speculations about life’s emergence to natural processes driven by diurnal physicochemical gradients, primarily of temperature, water activity and electromagnetic radiation. First, Earth’s prebiotic chemical evolution is historically continuous with Darwinian evolution; second, cycling energies of solar radiation are primary drivers of chemical evolution; third, environmental molecular complexity must be high at the origin of life; and fourth, non-covalent molecular forces determine molecular recognition and cellular organization. Under normal physiological conditions of high ionic strength and high macromolecular crowding, hydration interactions (hydrogen bonding), screened electrostatic forces and excluded volume repulsions act over acommensuratedistance of about one nanometer. This intermolecular distance governs chemical coevolution of proto-biomacromolecular surfaces (nucleic acids, proteins and membranes) toward Darwinian thresholds and living states. The above physicochemical principles of life’s emergence are consistent with the second law of thermodynamics, and with the current facts of molecular microbiology and planetary sciences. New kinds of experimentation with crowded molecular mixtures under oscillating temperature gradients - a PCR-like mechanism of life’s origins - can further illuminate how living states come about.Graphical abstractLife’s emergence follows from chemical and Darwinian evolution, a high degree of molecular complexity and a high crowdedness, and non-covalent molecular forces that determine molecular recognition and cellular organization. The macromolecules divide the cytoplasm into dynamically crowded macromolecular regions and topologically complementary electrolyte pools. Small ions and ionic metabolites are transported vectorially between the electrolyte pools and through the (semi-conducting) electrolyte pathways of the crowded macromolecular regions.

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