Enhanced electrochemical performances of layered LiNi0.5Mn0.5O2 as cathode materials by Ru doping for lithium-ion batteries

Ionics ◽  
2016 ◽  
Vol 22 (8) ◽  
pp. 1501-1508 ◽  
Author(s):  
Chun-Feng Sun ◽  
Nagdev Amruthnath ◽  
Jin-Shuai Yu ◽  
Wen-Jun Li
2015 ◽  
Vol 3 (5) ◽  
pp. 2025-2035 ◽  
Author(s):  
Qingyu Li ◽  
Fenghua Zheng ◽  
Youguo Huang ◽  
Xiaohui Zhang ◽  
Qiang Wu ◽  
...  

The solid state reaction method was applied to prepare a series of LiFePO4/C materials by adding various surfactants. The as-prepared LiFePO4/C particles using various surfactants show different electrochemical performances.


2013 ◽  
Vol 743-744 ◽  
pp. 35-43
Author(s):  
Shi Ming Zhang ◽  
Jun Xi Zhang ◽  
Bo Cheng He ◽  
Suo Jiong Xu ◽  
Xu Ji Yuan

nanosized FePO4 and Fe1-xCexPO4 (x=0.02, 0.04, 0.08) cathode materials were synthesized by microemulsion method. The samples were prepared via a microemulsion system in a H2O/cyclohexane/Triton x-100/n-butyl alcohol at different temperatures (30 , 45 , 50 , 60 ) and then sintered at 380 and 460 for 3 h. The thermal stability, structure and morphology were investigated by means of TG/DCS, X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), and the electrochemical properties were characterized by cyclic voltammetry (CV) and galvanostatic charge and discharge tests. Results show that synthesis temperature has a great influence on the performances of FePO4, and the sample synthesized at 45 shows the best performances with a diameter of about 20 nm and a high discharge initial specific capacity of 142mAh/g and retaining 123mAh/g after 20 cycles at 0.1 C. The Ce-doped FePO4, Fe1-xCexPO4 (x=0.02, 0.04, 0.08), can effectively improve the electrochemical properties of FePO4 cathode materials. The Fe0.96Ce0.04PO4 exhibits an initial discharge capacity of 158.2mAh/g and retains 152mAh/g after 20 cycles at 0.1 C. Hence, Fe0.96Ce0.04PO4 is a promising candidate for cathode materials of lithium ion batteries.


2015 ◽  
Vol 3 (23) ◽  
pp. 12320-12327 ◽  
Author(s):  
Li Liu ◽  
Huijuan Zhang ◽  
Xi Chen ◽  
Ling Fang ◽  
Yuanjuan Bai ◽  
...  

Herein, the unique two-layered sandwiched graphene@(Li0.893Fe0.036)Co(PO4) nanoparticles, which presents outstanding electrochemical performances, have been successfully fabricated through the template-sacrificial method.


2020 ◽  
Vol 49 (14) ◽  
pp. 4667-4680 ◽  
Author(s):  
Luyi Yang ◽  
Kai Yang ◽  
Jiaxin Zheng ◽  
Kang Xu ◽  
Khalil Amine ◽  
...  

The impact of surface structure and interface reconstruction on the electrochemical performances of lithium-ion battery cathode materials is summarized.


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