Optimize the surface of the Li-rich cathode materials with lithium phosphate and polyaniline to improve the electrochemical performance

Ionics ◽  
2021 ◽  
Author(s):  
Xing Li ◽  
Xincun Tang ◽  
Kun Ouyang ◽  
Ping Deng ◽  
Liuchun Huang ◽  
...  
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xing Shen ◽  
Quan Zhou ◽  
Miao Han ◽  
Xingguo Qi ◽  
Bo Li ◽  
...  

AbstractNa-ion batteries have been considered promising candidates for stationary energy storage. However, their wide application is hindered by issues such as high cost and insufficient electrochemical performance, particularly for cathode materials. Here, we report a solvent-free mechanochemical protocol for the in-situ fabrication of sodium vanadium fluorophosphates. Benefiting from the nano-crystallization features and extra Na-storage sites achieved in the synthesis process, the as-prepared carbon-coated Na3(VOPO4)2F nanocomposite exhibits capacity of 142 mAh g−1 at 0.1C, higher than its theoretical capacity (130 mAh g−1). Moreover, a scaled synthesis with 2 kg of product was conducted and 26650-prototype cells were demonstrated to proof the electrochemical performance. We expect our findings to mark an important step in the industrial application of sodium vanadium fluorophosphates for Na-ion batteries.


2011 ◽  
Vol 214 (3) ◽  
pp. 279-282 ◽  
Author(s):  
Peng Yue ◽  
Zhixing Wang ◽  
Wenjie Peng ◽  
Lingjun Li ◽  
Wei Chen ◽  
...  

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