Effect of Alloying Additions on Phase Equilibria and Creep Resistance of Alumina-Forming Austenitic Stainless Steels

2009 ◽  
Vol 40 (8) ◽  
pp. 1868-1880 ◽  
Author(s):  
Y. Yamamoto ◽  
M.L. Santella ◽  
M.P. Brady ◽  
H. Bei ◽  
P.J. Maziasz
2009 ◽  
Vol 131 (5) ◽  
Author(s):  
Philip J. Maziasz ◽  
John P. Shingledecker ◽  
Neal D. Evans ◽  
Michael J. Pollard

Oak Ridge National Laboratory and Caterpillar (CAT) have recently developed a new cast austenitic stainless steel, CF8C-Plus, for a wide range of high-temperature applications, including diesel exhaust components and turbine casings. The creep-rupture life of the new CF8C-Plus is over ten times greater than that of the standard cast CF8C stainless steel, and the creep-rupture strength is about 50–70% greater. Another variant, CF8C-Plus Cu/W, has been developed with even more creep strength at 750–850°C. The creep strength of these new cast austenitic stainless steels is close to that of wrought Ni-based superalloys such as 617. CF8C-Plus steel was developed in about 1.5 years using an “engineered microstructure” alloy development approach, which produces creep resistance based on the formation of stable nanocarbides (NbC), and resistance to the formation of deleterious intermetallics (sigma, Laves) during aging or service. The first commercial trial heats (227.5 kg or 500 lb) of CF8C-Plus steel were produced in 2002, and to date, over 27,215 kg (300 tons) have been produced, including various commercial component trials, but mainly for the commercial production of the Caterpillar regeneration system (CRS). The CRS application is a burner housing for the on-highway heavy-duty diesel engines that begins the process to burn-off particulates trapped in the ceramic diesel particulate filter (DPF). The CRS/DPF technology was required to meet the new more stringent emissions regulations in January, 2007, and subjects the CRS to frequent and severe thermal cycling. To date, all CF8C-Plus steel CRS units have performed successfully. The status of testing for other commercial applications of CF8C-Plus steel is also summarized.


Author(s):  
Philip J. Maziasz ◽  
John P. Shingledecker ◽  
Neal D. Evans ◽  
Michael J. Pollard

Oak Ridge National Laboratory (ORNL) and Caterpillar have recently developed a new cast austenitic stainless steel, CF8C-Plus, for a wide range of high-temperature applications, including diesel exhaust components and turbine casings. The creep-rupture life of the new CF8C-Plus is over ten times greater than that of the standard cast CF8C stainless steel, and the creep-strength is about double. Another variant, CF8C-Plus Cu/W has been developed with even more creep strength at 750–850°C. The creep-strength of these new cast austenitic stainless steels is close to that of Ni-based superalloys like 617. CF8C-Plus steel was developed in about 1.5 years using an “engineered microstructure” alloy development approach, which produces creep resistance based on formation of stable nano-carbides (NbC) and prevention of deleterious intermetallics (sigma, Laves). CF8C-Plus steel won a 2003 R&D 100 Award, and to date, over 32,000 lb have been produced in various commercial component trials. The current commercialization status of the alloy is summarized.


Author(s):  
E.A. Kenik ◽  
P.J. Maziasz ◽  
R.L. Klueh

Development of manganese-stabilized stainless steels has been prompted by two objectives: (1) replacement of nickel, normally used to stabilize austenitic stainless steels, since it is an expensive, strategic material, and (2) reduction of long-term induced radioactivity of neutron-irradiated stainless steels by replacing nickel, molybdenum, and nitrogen. Klueh et al. have shown that in Fe-Cr-Mn alloys a single-phase austenite exists near Fe-12Cr-20Mn-0.25C (wt %) at high temperatures. Development of more complex alloys based on this composition with other minor alloying additions is underway. The aim is to develop alloys with improved mechanical properties, while minimizing the formation of embrittling second phases such as sigma or Laves. The stability of these alloys during thermal aging and the influence of the other alloying additions was studied in the current work for both solution-annealed and cold-worked conditions.Seven alloys based on Fe-12Cr-20Mn-0.25C were made with additions of W, Ti, V, P, and B, either singly or in combination. The alloys were hot-worked and subsequently cold-worked to sheet with intermediate anneals at 1150°C. Materials were aged at 600°C for 5000 h in both 20% cold-worked and annealed (1 h, 1050°C) conditions.


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