A new model and estimation of thermodynamic parameters for the solubility of azobenzene and anthraquinone derivatives in supercritical carbon dioxide

2021 ◽  
Author(s):  
Ratna Surya Alwi ◽  
Chandrasekhar Garlapati
Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 460
Author(s):  
Ratna Surya Alwi ◽  
Chandrasekhar Garlapati ◽  
Kazuhiro Tamura

Solubility of several anthraquinone derivatives in supercritical carbon dioxide was readily available in the literature, but correcting ability of the existing models was poor. Therefore, in this work, two new models have been developed for better correlation based on solid–liquid phase equilibria. The new model has five adjustable parameters correlating the solubility isotherms as a function of temperature. The accuracy of the proposed models was evaluated by correlating 25 binary systems. The proposed models observed provide the best overall correlations. The overall deviation between the experimental and the correlated results was less than 11.46% in averaged absolute relative deviation (AARD). Moreover, exiting solubility models were also evaluated for all the compounds for the comparison purpose.


1998 ◽  
Vol 43 (3) ◽  
pp. 400-402 ◽  
Author(s):  
Mohammad Reza Fat'hi ◽  
Yadollah Yamini ◽  
Hashem Sharghi ◽  
Mojtaba Shamsipur

2013 ◽  
Vol 561 ◽  
pp. 91-97 ◽  
Author(s):  
Ramachandran Sridar ◽  
Avijit Bhowal ◽  
Chandrasekhar Garlapati

2004 ◽  
Vol 32 (1-3) ◽  
pp. 47-53 ◽  
Author(s):  
Mojtaba Shamsipur ◽  
Ali Reza Karami ◽  
Yadollah Yamini ◽  
Hashem Sharghi

2015 ◽  
Vol 19 (4) ◽  
pp. 1283-1286 ◽  
Author(s):  
Juan Zhang ◽  
Lai-Jiu Zheng ◽  
Yu-Ping Zhao ◽  
Jun Yan ◽  
Xiao-Qing Xiong ◽  
...  

Green dyeing process with zero waste water emission is a hot topic recently. This paper reveals that supercritical carbon dioxide is the best candidate for this purpose. Effects of thermodynamic parameters, such as enthalpy and entropy of activation, on dyeing process are studied experimentally.


2019 ◽  
Vol 166 ◽  
pp. 330-339 ◽  
Author(s):  
Raju Penthala ◽  
Rangaraju Satish Kumar ◽  
Gisu Heo ◽  
Hyorim Kim ◽  
In Yeol Lee ◽  
...  

2017 ◽  
Author(s):  
Ratna Surya Alwi ◽  
Kazuhiro Tamura ◽  
Tatsuro Tanaka ◽  
Keisuke Shimizu

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