Thermoreversible and Recycling Properties of Ethylene Propylene Diene Rubber Based on Diels-Alder Reaction

2021 ◽  
Vol 29 (8) ◽  
pp. 543-550
Author(s):  
Chong Sun ◽  
Yehua Jiang ◽  
Zhifei Zhang ◽  
Shugao Zhao ◽  
Laina Guo
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Ethylene Propylene ◽  
Diels Alder Reaction ◽  
Ethylene Propylene Diene Rubber ◽  
Diene Rubber

Studies on a New Antireversion Agent for Sulfur Vulcanization of Diene Rubbers

1996 ◽  
Vol 69 (5) ◽  
pp. 727-741 ◽  
Author(s):  
A. H. M. Schotman ◽  
P. J. C. van Haeren ◽  
A. J. M. Weber ◽  
F. G. H. van Wijk ◽  
J. W. Hofstraat ◽  
...  
Keyword(s):  
Crosslink Density ◽  
Alder Reaction ◽  
Diels Alder ◽  
Spectroscopic Methods ◽  
Diels Alder Reaction ◽  
Sulfur Vulcanization ◽  
Cure Time ◽  
Conjugated Polyenes ◽  
Diene Rubbers ◽  
Diene Rubber

Abstract The mechanism of biscitraconimides (BCI) as antireversion agents for sulfur vulcanized diene rubber was investigated choosing squalene as a model substrate. Curing of squalene with sulfur in the presence of accelerator, activator and BCI at 170°C gave BCI bridged adducts. The products were identified by spectroscopic methods as being results of a Diels-Alder reaction of BCI (dienophile) with conjugated polyenes that are formed as a result of reversion. The rate at which the sulfur network degrades is comparable to the rate in which BCI adduct is formed. As a result of this, a nearly constant crosslink density is obtained after optimum cure time (t90). Based on this concept, the advantage of using 1,3-bis-(citraconimidomethyl) benzene (BCI-MX), a representative of the BCI-class, in NR based compounds is examined.

The Diels-Alder Reaction of 2-Ethenyl-1,4-Benzodioxin: A New and Simple Synthesis of Bisaryl Ethers

Synlett ◽  
1989 ◽  
Vol 1989 (01) ◽  
pp. 30-32
Author(s):  
Thomas V. Lee ◽  
Alistair J. Leigh ◽  
Christopher B. Chapleo
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Simple Synthesis ◽  
Diels Alder Reaction

The intermolecular anthracene-transfer in a regiospecific antipodal C60 difunctionalization

2020 ◽  
Author(s):  
Radu Talmazan ◽  
Klaus R. Liedl ◽  
Bernhard Kräutler ◽  
Maren Podewitz
Keyword(s):  
Noncovalent Interactions ◽  
Interaction Model ◽  
Alder Reaction ◽  
Diels Alder ◽  
Stacking Interactions ◽  
Pi Stacking ◽  
Diels Alder Reaction ◽  
Double Decker ◽  
Anthracene Molecule ◽  
New Strategies

We analyze the mechanism of the topochemically controlled difunctionalization of C60 and anthracene, where an anthracene molecule is transferred from one C60 monoadduct to another one under exclusive formation of equal amounts of C60 and the difficult to make antipodal C60 bisadduct. Our herein disclosed dispersion corrected DFT studies show the anthracene transfer to take place in a synchronous retro Diels-Alder/Diels-Alder reaction: an anthracene molecule dissociates from one fullerene under formation of an intermediate, while already undergoing stabilizing interactions with both neighboring fullerenes, facilitating the reaction kinetically. In the intermediate, a planar anthracene molecule is sandwiched between two neighboring fullerenes and forms equally strong "double-decker" type pi-pi stacking interactions with both of these fullerenes. Analysis with the distorsion interaction model shows that the anthracene unit of the intermediate is almost planar with minimal distorsions. This analysis sheds light on the existence of noncovalent interactions engaging both faces of a planar polyunsaturated ring and two convex fullerene surfaces in an unprecedented 'inverted sandwich' structure. Hence, it sheds light on new strategies to design functional fullerene based materials.<br>

Natural Products Biosynthesis Involving a Putative Diels-Alder Reaction

2016 ◽  
Vol 20 (22) ◽  
pp. 2421-2442 ◽  
Author(s):  
Kévin Cottet ◽  
Maria Kolympadi ◽  
Dean Markovic ◽  
Marie-Christine Lallemand
Keyword(s):  
Natural Products ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Aza-Diels-Alder Reaction Between 1,2-Diaza-1,3-dienes and β-Aryl-α,β-unsaturated Carbonyl Compounds. Easy One-pot Entry to 2’-Oxo-imidazo[1’,5’- f]tetrahydropyridazine

2014 ◽  
Vol 10 (6) ◽  
pp. 951-960
Author(s):  
Orazio Attanasi ◽  
Luca Bianchi ◽  
Maurizio D’Auria ◽  
Gianfranco Favi ◽  
Fabio Mantellini ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Alder Reaction ◽  
Diels Alder ◽  
One Pot ◽  
Diels Alder Reaction

Enantioselective Syntheses of Flavonoid Diels-Alder Natural Products: A Review

2018 ◽  
Vol 15 (2) ◽  
pp. 221-229 ◽  
Author(s):  
Shah Bakhtiar Nasir ◽  
Noorsaadah Abd Rahman ◽  
Chin Fei Chee
Keyword(s):  
Natural Products ◽  
Organic Synthesis ◽  
Lewis Acid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Enantioselective Synthesis ◽  
Chiral Ligand ◽  
Asymmetric Syntheses ◽  
Diels Alder Reaction ◽  
Enantioselective Syntheses

Background: The Diels-Alder reaction has been widely utilised in the syntheses of biologically important natural products over the years and continues to greatly impact modern synthetic methodology. Recent discovery of chiral organocatalysts, auxiliaries and ligands in organic synthesis has paved the way for their application in Diels-Alder chemistry with the goal to improve efficiency as well as stereochemistry. Objective: The review focuses on asymmetric syntheses of flavonoid Diels-Alder natural products that utilize chiral ligand-Lewis acid complexes through various illustrative examples. Conclusion: It is clear from the review that a significant amount of research has been done investigating various types of catalysts and chiral ligand-Lewis acid complexes for the enantioselective synthesis of flavonoid Diels-Alder natural products. The results have demonstrated improved yield and enantioselectivity. Much emphasis has been placed on the synthesis but important mechanistic work aimed at understanding the enantioselectivity has also been discussed.

DMF. I2 Complex as Efficient Green Catalyst in the Diels-alder Reaction of Anthracene-9-Methanol with Maleimide

2017 ◽  
Vol 4 (1) ◽  
Author(s):  
Urbain C. Kassehin ◽  
Sèdami M. Fagla ◽  
Fernand A. Gbaguidi ◽  
Julien R. C. Prevost ◽  
Raphaël Frédérick ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Green Catalyst ◽  
Diels Alder Reaction
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