scholarly journals Stability, reusability, and equivalent circuit of TiO2/treated metakaolinite-based dye-sensitized solar cell: effect of illumination intensity on Voc and Isc values

Author(s):  
Winda Rahmalia ◽  
Imelda H. Silalahi ◽  
Thamrin Usman ◽  
Jean-François Fabre ◽  
Zéphirin Mouloungui ◽  
...  

AbstractIn this research, treated metakaolinite (TMK) was introduced into the TiO2 photoelectrode to fabricated dye-sensitized solar cells (DSSCs). The photovoltaic cells have four main natural components, i.e., a photosensitizer (carotenoid bixin), photoelectrode (TiO2/kaolinite), electrolyte (glycerine carbonate derivative), and counter-electrode (carbon). Their stability, reusability, and equivalent circuit were studied. The presence of 5% of TMK in anatase TiO2 paste decreased the TiO2 band gap from 3.21 to 3.16 eV. The result showed that the presence of 5% of TMK in TiO2 paste was more favorable to obtain higher energy conversion efficiency. Under a light intensity of 200 W/m2, it produced an energy conversion yield of 0.086%. The combination of the electrolyte and the TMK demonstrated a synergistic effect to improve the electrical properties of the DSSC. The energy storage function worked well until the third day of analysis. The DSSC based on TiO2/TMK photoelectrode exhibited 16 times better stability than pure TiO2-based photoelectrode. The Faraday charge transfer processes showed that the TiO2/TMK photoelectrode is not in direct contact with the carbon counter-electrode.

2014 ◽  
Vol 2 (41) ◽  
pp. 17253-17257 ◽  
Author(s):  
Xiao Chen ◽  
Yu Hou ◽  
Shuang Yang ◽  
Xiao Hua Yang ◽  
Hua Gui Yang

A novel strategy was introduced to prepare Pt–SnO2 nanocomposite in one step. Pt–SnO2 nanocomposite counter electrode based dye-sensitized solar cells achieve an energy conversion efficiency of 8.83%, better than that for SnO2 CE and comparable with Pt CE based DSCs.


2008 ◽  
Vol 1102 ◽  
Author(s):  
Prakash Joshi ◽  
Yu Xie ◽  
Jeremiah Mwaura ◽  
Mike Ropp ◽  
David Galipeau ◽  
...  

AbstractWe report dye-sensitized solar cells using low cost carbon nanoparticles as an alternative to platinum as a counter-electrode catalyst for triiodide reduction. The counter carbon-electrode was deposited onto fluorine-doped tin oxide (FTO) by spin coating from an aqueous colloidal suspension of the blend of carbon nanoparticles and TiO2 nanocrystals. DSSC devices were fabricated using a stable Ru complex dye (Z-907) as the sensitizer. The cells based on carbon-nanoparticle counter electrode were made and then compared with those cells from platinum counter electrode at similar fabrication conditions. The results have shown that the device performance in terms of short circuit current density (Jsc), open circuit voltage (Voc) and energy conversion efficiency (η) from the cells based on carbon nanoparticle counter electrode were comparable to those from platinum counter-electrode devices. The carbon nanoparticle based cells have achieved an overall energy conversion efficiency of 5.55% under one sun AM 1.5 illumination (100 mW/cm2). The carbon nanoparticles showed significant potential as a low cost alternative to the current widely-used platinum.


RSC Advances ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 8307-8310 ◽  
Author(s):  
Xiao Chen ◽  
Jian Wei Guo ◽  
Yu Hou ◽  
Yu Hang Li ◽  
Shuang Yang ◽  
...  

PtO–MWCNTs nanocomposites were prepared and applied as the counter electrode in dye-sensitized solar cells (DSCs) for the first time. Excellent energy conversion efficiency indicated that the nanocomposite was a promising electrocatalyst for DSCs.


RSC Advances ◽  
2016 ◽  
Vol 6 (87) ◽  
pp. 83802-83807 ◽  
Author(s):  
Yu Hou ◽  
Shuang Yang ◽  
Chunzhong Li ◽  
Huijun Zhao ◽  
Hua Gui Yang

An energy conversion efficiency of 8.31% is reached by using a cemented photoanode for dye-sensitized solar cells, attaining a 31.1% improvement over the standard Degussa P25 sample.


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