Reduction of hexavalent chromium concentration in fumes from metal cored arc welding by addition of reactive metals

1996 ◽  
Vol 40 (3) ◽  
pp. 339-344 ◽  
Author(s):  
J DENNIS
1998 ◽  
Vol 14 (04) ◽  
pp. 246-254
Author(s):  
Bhaskar Kura ◽  
Praveen Mookoni

The Occupational Safety and Health Administration is expected to reduce permissible exposure limits of hexavalent chromium from 100 ng/m3between 5 to 0.5 fig/m3. A Navy Industry Task Group study revealed that the impact of proposed regulations on the shipbuilding industry is significant. The estimated cost of compliance by the Navy facilities could be as much as $46 Million/year besides a one-time cost of about $22 Million. Also, the task group estimated that the cost of $9 Million. This paper presents the results of a study undertaken at the University of New Orleans in support of the Navy/Industry Task Group efforts. The study included assessments of Cr(VI) exposure levels for two specific welding processes and three welding scenarios. Airborne particulate matter was collected using personal samplers for two specific welding processes, Gas Metal Arc Welding and Flux-Cored Arc Welding. Two base metals, HY100 and DH36, were considered for Flux-Cored Arc Welding and one base metal, HY100, was considered for Gas Metal Arc Welding. The samples were analyzed for Cr(VI) using OSHA Method 215. Based on the data generated, it can be concluded that Gas Metal Arc Welding and Flux-Cored Arc Welding on HY100 steel result in 8-hr. worker exposures less than 0.5 fig/m3 in a laboratory type setting, though the same levels of exposure may be difficult to be achieved in the field. Flux-Cored Arc Welding on DH36 resulted in exposure above 0.5 ng/m3, again in laboratory type setting.


1992 ◽  
Vol 11 (4) ◽  
pp. 259-263 ◽  
Author(s):  
Jens Peter Bonde ◽  
Erik Ernst

Recent experimental studies in rodents document the spermatotoxic effects of watersoluble hexavalent chromium. Welders comprise, worldwide, a major occupational group with acknowledged exposure to chromium. This study examines the relationship between semen quality and chromium in the urine and blood of a population of 30 tungsten inert gas (TIG) stainless steel welders, 30 mild steel welders and 47 non-welding workers. Each subject provided two to three semen samples. The chromium concentration ranged from 0.17 to 4.74 nmol mmol1 creatinine (median 1.08) in post-shift spot urine and from 6.0 to 46.4 nmol 1-1 in blood. None of several semen parameters deteriorated with increasing level of internal exposure to chromium. Low-level exposure to hexavalent chromium associated with TIG stainless steel and mild steel welding do not appear to be a major hazard for human spermatogenesis.


2018 ◽  
Vol 13 (1) ◽  
pp. 115-124
Author(s):  
Benjamin David Martin ◽  
Mohammed Qasim Asghar ◽  
Eve Germain

Abstract Hexavalent chromium is difficult to remove during conventional biological wastewater treatment. This is because the hexavalent form is dissolved and is only sparingly removed by adsorption onto biomass in conventional processes. Hexavalent chromium is of particular concern because of its aquatic toxicity, and an increasing number of wastewater works have effluent discharge limits to protect receiving water courses, some as low as 8 μg Cr L−1. A relatively simple improvement to the removal of chromium could be made by switching the aluminium or ferric solution dosed at most treatment works for the removal of solids, organic load and phosphorus, to a ferrous salt. Ferrous reduces hexavalent chromium to insoluble trivalent chromium, which can be readily settled out of waste streams as a particulate. In the present study, laboratory experiments using real wastewater and ferrous doses of 10 mg Fe L−1 achieve the chromium discharge consent of 8 μg L−1 from initial solution concentrations of up to 40 μg L−1. A ferrous chloride dosing system was subsequently installed at an operational sewage treatment works that has produced an average final effluent chromium concentration of 2.4 μg L−1 (with a maximum of 4.2 μg L−1), despite influent spikes >300 μg L−1.


2016 ◽  
Vol 74 (10) ◽  
pp. 2305-2313 ◽  
Author(s):  
Majid Riahi Samani ◽  
Parisa Ebrahimbabaie ◽  
Hamed Vafaei Molamahmood

Over the past few years, heavy metals have been proved to be one of the most important contaminants in industrial wastewater. Chromium is one of these heavy metals, which is being utilized in several industries such as textile, finishing and leather industries. Since hexavalent chromium is highly toxic to human health, removal of it from the wastewater is essential for human safety. One of the techniques for removing chromium (VI) is the use of different adsorbents such as polyaniline. In this study, composites of polyaniline (PANi) were synthesized with various amounts of polyvinyl alcohol (PVA). The results showed that PANi/PVA removed around 76% of chromium at a pH of 6.5; the PVA has altered the morphology of the composites and increased the removal efficiency. Additionally, synthesis of 20 mg/L of PVA by PANi composite showed the best removal efficiency, and the optimal stirring time was calculated as 30 minutes. Moreover, the chromium removal efficiency was increased by decreasing the pH, initial chromium concentration and increasing stirring time.


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