Kinetics of coke deposition in the thermal cracking of propane

1979 ◽  
Vol 34 (5) ◽  
pp. 635-644 ◽  
Author(s):  
K.M. Sundaram ◽  
G.F. Froment
2020 ◽  
Vol 145 ◽  
pp. 1761-1771 ◽  
Author(s):  
Jie Li ◽  
Yuanyu Tian ◽  
Peijie Zong ◽  
Yingyun Qiao ◽  
Song Qin

Fuel ◽  
1985 ◽  
Vol 64 (11) ◽  
pp. 1591-1598 ◽  
Author(s):  
Karen S. Yoshiki ◽  
Colin R. Phillips

2021 ◽  
Author(s):  
Yuliana Rodriguez Lamar ◽  
José Noboa ◽  
Andrés S. Torres Miranda ◽  
Daniela Almeida Streitwieser

Abstract The inappropriate disposal of plastic waste cause serious environmental problems. Nowadays, alternative processes are being studied for the sustainable reutilization of plastics. One of these options is the cracking into shorter liquid hydrocarbon fractions, while maintaining its basic chemical structure. The energetic potential from the original plastics structure remains and the fractions can be used as fuels and chemical precursors. This research addresses the kinetic study of thermal cracking of polypropylene (PP) and high- and low-density polyethylene (HDPE and LDPE) in a batch reactor. The kinetics of the reaction can be described as a first-order rate with the lowest activation energy using PP, followed by HDPE and LDPE with values of 367.28 kJ/mol, 453.37 kJ/mol and 457.96 kJ/mol, respectively. The yield obtained for the liquid fraction is highest for LDPE, with a value of 72% at 390°C, followed by HDPE and LDPE with 69% and 62% at 375°C. The liquid fractions obtained from the process were characterized according to ASTM standards, obtaining that LDPE and HDPE fractions have similar properties to diesel, while PP is closer to gasoline. The fractions were also analyzed by means of gas chromatography identifying the main products of the reaction and establishing a possible reaction mechanism.


Author(s):  
Ramin Karimzadeh ◽  
Amin Hematian ◽  
Mohammad Reza Omidkhah

Various parameters such as type of feedstock, inlet and outlet coil temperature, heat flux and residence time, affect the performance of a thermal cracking reactor. The pyrolysis coil configuration is one of the most important parameters which affects the performance of the reactor.In this research the effect of four different coil configurations, namely single row, millisecond, split and reversed split have been studied on run length, product yields, outside surface temperature of coil, coke deposition as well as temperature and pressure distribution. The reactor under investigation is the thermal cracker of Abadan petrochemical complex which uses propane as feedstock. The results show that millisecond coil configuration has the highest yield of ethylene and lowest coke thickness. However, it exhibits the lowest run length and worst ratio of length to diameter conditions. On the other hand, single row coil configuration has the lowest ethylene yield and highest coke thickness but, the highest run length with the lowest pressure drop also belongs to this coil configuration. It also presents the most even distribution of pressure and a linear temperature profile across the coil length, favoring better selectivity.


1989 ◽  
Vol 25 (3) ◽  
pp. 143-147
Author(s):  
�. A. Raud ◽  
M. A. Lioznov ◽  
E. Yu. Yushina ◽  
E. V. Smidovich

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