Total characterisation of the excited-state density matrix in laser fluorescence experiments

1984 ◽  
Vol 105 (5) ◽  
pp. 477-479 ◽  
Author(s):  
A.J. Bain ◽  
A.J. McCaffery
Keyword(s):  
Excited State ◽  
Density Matrix ◽  
State Density ◽  
Laser Fluorescence

scholarly journals Classical Chaos Described by a Density Matrix

Physics ◽  
2021 ◽  
Vol 3 (3) ◽  
pp. 739-746
Author(s):  
Andres Mauricio Kowalski ◽  
Angelo Plastino ◽  
Gaspar Gonzalez
Keyword(s):  
Density Matrix ◽  
Pure State ◽  
Classical Limit ◽  
Degrees Of Freedom ◽  
Temporal Evolution ◽  
Entropy Density ◽  
State Density ◽  
Unexpected Result ◽  
Semiclassical Model ◽  
Classical Chaos

In this paper, a reference to the semiclassical model, in which quantum degrees of freedom interact with classical ones, is considered. The classical limit of a maximum-entropy density matrix that describes the temporal evolution of such a system is analyzed. Here, it is analytically shown that, in the classical limit, it is possible to reproduce classical results. An example is classical chaos. This is done by means a pure-state density matrix, a rather unexpected result. It is shown that this is possible only if the quantum part of the system is in a special class of states.

scholarly journals 8-(Pyridin-2-yl)quinolin-7-ol as a Platform for Conjugated Proton Cranes: A DFT Structural Design

Micromachines ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 901 ◽  
Author(s):  
Anton Georgiev ◽  
Liudmil Antonov
Keyword(s):  
Excited State ◽  
Structural Design ◽  
Density Functional ◽  
Intramolecular Proton Transfer ◽  
State Density ◽  
Strong Electron ◽  
Functional Theory ◽  
Substituted Pyridines ◽  
Donor Acceptor ◽  
Enol Tautomer

Theoretical design of conjugated proton cranes, based on 7-hydroxyquinoline as a tautomeric sub-unit, has been attempted by using ground and excited state density functional theory (DFT) calculations in various environments. The proton crane action request existence of a single enol tautomer in ground state, which under excitation goes to the excited keto tautomer through a series of consecutive excited-state intramolecular proton transfer (ESIPT) steps with the participation of the crane sub-unit. A series of substituted pyridines was used as crane sub-units and the corresponding donor-acceptor interactions were evaluated. The results suggest that the introduction of strong electron donor substituents in the pyridine ring creates optimal conditions for 8-(pyridin-2-yl)quinolin-7-ols to act as proton cranes.

scholarly journals Excited-state density functional theory

2012 ◽  
Vol 388 (1) ◽  
pp. 012011 ◽  
Author(s):  
Manoj K Harbola ◽  
M Hemanadhan ◽  
Md Shamim ◽  
P Samal
Keyword(s):  
Density Functional Theory ◽  
Excited State ◽  
Density Functional ◽  
State Density ◽  
Functional Theory

scholarly journals Iterative solutions to the steady-state density matrix for optomechanical systems

2015 ◽  
Vol 91 (1) ◽  
Author(s):  
P. D. Nation ◽  
J. R. Johansson ◽  
M. P. Blencowe ◽  
A. J. Rimberg
Keyword(s):  
Steady State ◽  
Density Matrix ◽  
State Density ◽  
Optomechanical Systems ◽  
Iterative Solutions
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