The valence states of manganese ion in potassium-borate oxide glasses

1984 ◽  
Vol 52 (2) ◽  
pp. 147-149 ◽  
Author(s):  
I. Ardelean ◽  
Gh. Ilonca ◽  
M. Peteanu
2002 ◽  
Vol 16 (07) ◽  
pp. 231-239 ◽  
Author(s):  
I. ARDELEAN ◽  
P. PASCUTA ◽  
M. PETEANU

EPR and magnetic susceptibility measurements have been performed on x Fe 2 O 3·(100-x) [3B2O3·CaO] glasses with 0<x≤40 mol%. The Fe 3+ ions in sites of distorted octahedral symmetry and clustered formations containing both Fe 3+ and Fe 2+ ionic species were found. Dipolar and magnetic super-exchange interactions involving iron ions were revealed to depend on the iron content of the sample.


2019 ◽  
Vol 123 (9) ◽  
pp. 5591-5602 ◽  
Author(s):  
Gangareddy Jagannath ◽  
Bheemaiah Eraiah ◽  
Anuraag Gaddam ◽  
Hugo Fernandes ◽  
Daniela Brazete ◽  
...  

2012 ◽  
Vol 27 (16) ◽  
pp. 2116-2121 ◽  
Author(s):  
Viktor V. Kedrov ◽  
Ivan M. Shmytko ◽  
Semeon Z. Shmurak ◽  
Elena A. Kudrenko ◽  
Nikolay V. Klassen

Abstract


2018 ◽  
Vol 5 (13) ◽  
pp. 26290-26297 ◽  
Author(s):  
L. Srinivasa Rao ◽  
V. Ravi Kumar ◽  
P. Naresh ◽  
P. Venkateswara Rao ◽  
N. Veeraiah

1997 ◽  
Vol 32 (2) ◽  
pp. 191-196 ◽  
Author(s):  
I. Ardelean ◽  
Gh. Ilonca ◽  
S. Simon ◽  
S. Filip ◽  
T. Jurcut

Author(s):  
T. E. Mitchell ◽  
R. B. Schwarz

Traditional oxide glasses occur naturally as obsidian and can be made easily by suitable cooling histories. In the past 30 years, a variety of techniques have been discovered which amorphize normally crystalline materials such as metals. These include [1-3]:Rapid quenching from the vapor phase.Rapid quenching from the liquid phase.Electrodeposition of certain alloys, e.g. Fe-P.Oxidation of crystals to produce amorphous surface oxide layers.Interdiffusion of two pure crystalline metals.Hydrogen-induced vitrification of an intermetal1ic.Mechanical alloying and ball-milling of intermetal lie compounds.Irradiation processes of all kinds using ions, electrons, neutrons, and fission products.We offer here some general comments on the use of TEM to study these materials and give some particular examples of such studies.Thin specimens can be prepared from bulk homogeneous materials in the usual way. Most often, however, amorphous materials are in the form of surface films or interfacial films with different chemistry from the substrates.


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