An XPS study of the adsorption of Re onto ZrO2: interface formation and film growth

1991 ◽  
Vol 251-252 ◽  
pp. 1023-1028 ◽  
Author(s):  
C. Morant ◽  
L. Galán ◽  
J.M. Sanz ◽  
F. Rueda
1991 ◽  
Vol 251-252 ◽  
pp. A374
Author(s):  
C. Morant ◽  
L. Galán ◽  
J.M. Sanz ◽  
F. Rueda

1993 ◽  
Vol 309 ◽  
Author(s):  
G. Ruhl ◽  
R. Rehmet ◽  
M. Knoživá ◽  
S. Vepřek

AbstractWith the decreasing minimum feature size of integrated microcircuits, a low-temperature, chlorine-free CVD process is needed for the deposition of TiN diffusion barriers. A problem during the thermal deposition of titanium nitride from organometallic precursors, such as tetrakis(dimethylamido)titanium, is the high content of carbon in the films. In situ XPS study reveals that most of the carbon is present as CHx inclusions with a smaller but not negligible amount of carbidic component. This can be avoided by using ammonia, but the high rate of the reaction in the gas phase makes the control of the film growth difficult. Most of the problems can be resolved when using hydrogen afterglow.


1981 ◽  
Vol 19 (3) ◽  
pp. 431-436 ◽  
Author(s):  
R. P. Vasquez ◽  
F. J. Grunthaner

2009 ◽  
Vol 41 (10) ◽  
pp. 830-833 ◽  
Author(s):  
Yaroslav Polyak ◽  
Zdeněk Bastl

1993 ◽  
Vol 223 (2) ◽  
pp. 341-347 ◽  
Author(s):  
Leong G. Mar ◽  
Peter Y. Timbrell ◽  
Robert N. Lamb

1993 ◽  
Vol 20 (5) ◽  
pp. 416-420 ◽  
Author(s):  
S. Nowak ◽  
M. Collaud ◽  
G. Dietler ◽  
P. Schmutz ◽  
L. Schlapbach

1987 ◽  
Vol 101 ◽  
Author(s):  
David A. Mantell ◽  
T.E. Orlowski

ABSTRACTAn in situ XPS study is made of the AI film growth from TIBA using an ArF pulsed laser on Si (100) substrates. It is found that the film is formed by the photochemical decomposition of the organometaliic on the surface. A metallic film is formed by island growth. These islands are covered with an organometaliic fragment layer of partially decomposed TIBA. The consequences of these observations toward understanding how laser processing can create prenucleation regions that catalyze film growth at temperatures below standard CVD temperatures are discussed.


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