Polymer-metal interface formation and film growth on plasma and ion-treated polymer surfaces

1993 ◽  
Vol 20 (5) ◽  
pp. 416-420 ◽  
Author(s):  
S. Nowak ◽  
M. Collaud ◽  
G. Dietler ◽  
P. Schmutz ◽  
L. Schlapbach
2005 ◽  
Vol 871 ◽  
Author(s):  
K. Demirkan ◽  
A. Mathew ◽  
R. L. Opila

AbstractAl was thermally evaporated onto the conjugated semiconductor polymer, poly(2-methoxy-5,2′- ethyl-hexyloxy-phenylene vinylene) (MEH-PPV) in successive steps. Interface formation and chemical interactions between the polymer and Al were investigated by X-ray Photoelectron Spectroscopy (XPS) and synchrotron source Ultraviolet Photoelectron Spectroscopy (UPS). XPS analyses (angle resolved and sputtering depth profile) proved the formation of an insulating aluminum oxide layer at the polymer metal interface. The C-O bonds in the polymer decreased as more Al was evaporated on the MEH-PPV. Also reaction between Al and the carbon backbone of the polymer leading to the creation of carbon-metal bonds was observed. UPS analysis suggested the possibility of Al reacting with the phenylene ring of the polymer.


2013 ◽  
Vol 577-578 ◽  
pp. 225-228 ◽  
Author(s):  
Olaf van der Sluis ◽  
Joris J.C. Remmers ◽  
M.A.C. Thurlings ◽  
B.J. Welling ◽  
Sander P.M. Noijen

It is Common Practice for Polymer-Metal Interfaces, Frequently Encountered in Microelec-Tronic Devices, to Improve Adhesion by Surface Roughening or Micro-Patterning. the Competitionbetween Adhesive Fracture and Cohesive Fracture in the Vicinity of a Patterned Interface, i.e., Inter-Face Crack Deflection, is One of these Key Mechanisms that Contribute Significantly to the Macroscopicadhesion. in this Paper, these Fracture Phenomena are Described Simultaneously by Cohesive Zoneelements with an Exponential Traction-Separation Law (TSL) for the Adhesive Failure and an Initiallyrigid, Exponentially Decaying, TSL for the Cohesive Failure. it is Demonstrated that the Conditions Atwhich Crack Kinking Occurs are Dominated by Fracture Strength Values as Opposed to the Commonlyused Fracture Toughness Values. Experimental Verification is Performed by Means of Four Point Bend-Ing Tests on Specifically Designed Micro-Patterned Polymer-Metal Samples.


Author(s):  
T. Du ◽  
M. Liu ◽  
S. Seghi ◽  
K.J. Hsia ◽  
J. Economy ◽  
...  

1991 ◽  
Vol 251-252 ◽  
pp. A374
Author(s):  
C. Morant ◽  
L. Galán ◽  
J.M. Sanz ◽  
F. Rueda

Author(s):  
Timothy P. Ferguson ◽  
Jianmin Qu

Based on interfacial fracture mechanics and the hydrophobicity of the interface, en engineering model was developed in this paper. Using this model, one can predicted the degradation of interfacial fracture toughness of a polymer/metal interface once the moisture concentration near the interface is known.


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