Single crystals of Ni3(Al, M) were grown by the Bridgman method, where M is Ti, V, Cr, Mn, Fe, Nb, Mo and Ta. The composition was controlled to be about Ni75Al20
M
5 so that the alloying element, M, substitutes mainly for Al. With these crystals conventional X-ray structural analysis was performed. The measured static displacements of atoms from the average lattice points depended largely on the alloying elements and varied in the range 0.00–0.13 Å for Ni atoms and 0.09–0.18 Å for Al atoms. It was found that these atomic displacements correlated well with the atomic radius of the alloying element, M. For example, when the atomic radius of M is larger than that of Al, the static displacements are large for the atoms in the Al sublattice but small for the atoms in the Ni sublattice. By contrast, when the atomic radius of M is smaller than that of Al, the displacements are more enhanced in the Ni sublattice than in the Al sublattice. Thus, there is an interesting correlation between the atomic displacements in both the Al and Ni sublattices in the presence of alloying elements. This seems to be one of the characteristics of alloyed compounds with several sublattices.
Physicochemical Biology: Conquered Boundaries and New Horizons
