Production of Ni-Ru bimetallic catalysts and materials by thermal and chemical decomposition of a tetranuclear bimetallic carbonyl cluster

1991 ◽  
Vol 29 (1-4) ◽  
pp. 251-260 ◽  
Author(s):  
A. Armigliato ◽  
S. Bigi ◽  
P. Moggi ◽  
S. Papadopulos ◽  
G. Predieri ◽  
...  
Author(s):  
A. Sachdev ◽  
J. Schwank

Platinum - tin bimetallic catalysts have been primarily utilized in the chemical industry in the catalytic reforming of petroleum fractions. In this process the naphtha feedstock is converted to hydrocarbons with higher octane numbers and high anti-knock qualities. Most of these catalysts contain small metal particles or crystallites supported on high surface area insulating oxide supports. The determination of the structure and composition of these particles is crucial to the understanding of the catalytic behavior. In a bimetallic catalyst it is important to know how the two metals are distributed within the particle size range and in what way the addition of a second metal affects the size, structure and composition of the metal particles. An added complication in the Pt-Sn system is the possibility of alloy formation between the two elements for all atomic ratios.


2017 ◽  
Vol 68 (6) ◽  
pp. 1352-1356 ◽  
Author(s):  
Beatrice Gabriela Ioan ◽  
Cristiana Manea ◽  
Bianca Hanganu ◽  
Laura Statescu ◽  
Laura Gheuca Solovastru ◽  
...  

Human body is a complex of organic substances (proteins, lipids, carbohydrates), which undergo chemical decomposition processes soon after death. The compounds released during decomposition characterize the development of different stages of this process: e.g. biogenic amines resulted from the proteins decomposition will confer the particular smell of a cadaver, gases resulted from carbohydrates fermentation will give the bloating aspect of the cadaver. The study of cadaver decomposition and the products resulted from this process is the subject of human taphonomy and is realized nowadays in special facilities in USA and Australia. Identification and analysis of the chemical compounds emerged after human decomposition (gases, liquids, salts) give valuable information to forensic pathologists for estimating the postmortem interval (PMI). More, volatile compounds � which give the odor signature�specific to human remains � may be utilized in identifying clandestine burials, human remains or victims entrapped under ruins in cases of natural disasters. In this paper the authors describe the chemical decomposition stages of human cadavers, the factors influencing these processes and utility for the forensic activity of the results of human taphonomic studies.


Author(s):  
Sen-Wang Wang ◽  
Zhen-Hong He ◽  
Jian-Gang Chen ◽  
Kuan Wang ◽  
Zhong-Yu Wang ◽  
...  

Hydrogenolysis of biomass-derived lignin sources is highly important for the conversion of renewable biomass resources to biofuels. However, lots of developed catalysts suffer from the drawbacks of expensive precious metal...


2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Byung Chul Yeo ◽  
Hyunji Nam ◽  
Hyobin Nam ◽  
Min-Cheol Kim ◽  
Hong Woo Lee ◽  
...  

AbstractTo accelerate the discovery of materials through computations and experiments, a well-established protocol closely bridging these methods is required. We introduce a high-throughput screening protocol for the discovery of bimetallic catalysts that replace palladium (Pd), where the similarities in the electronic density of states patterns were employed as a screening descriptor. Using first-principles calculations, we screened 4350 bimetallic alloy structures and proposed eight candidates expected to have catalytic performance comparable to that of Pd. Our experiments demonstrate that four bimetallic catalysts indeed exhibit catalytic properties comparable to those of Pd. Moreover, we discover a bimetallic (Ni-Pt) catalyst that has not yet been reported for H2O2 direct synthesis. In particular, Ni61Pt39 outperforms the prototypical Pd catalyst for the chemical reaction and exhibits a 9.5-fold enhancement in cost-normalized productivity. This protocol provides an opportunity for the catalyst discovery for the replacement or reduction in the use of the platinum-group metals.


2021 ◽  
Vol 942 ◽  
pp. 121817
Author(s):  
Ying-Zhou Li ◽  
Zhi-Rui Yuan ◽  
Rakesh Ganguly ◽  
Yongxin Li ◽  
Deborah Roshni Rajaratnam ◽  
...  

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