High-pressure ultrasonic determination of the phase diagram of antiferromagnetic Cr-0.3 at.% Ru alloy single-crystal

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl2·7H2O at 2.50 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.

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Revision of the Li–Si Phase Diagram: Discovery and Single-Crystal X-ray Structure Determination of the High-Temperature Phase Li4.11Si

Chemistry of Materials ◽

10.1021/cm4029885 ◽

2013 ◽

Vol 25 (22) ◽

pp. 4623-4632 ◽

Cited By ~ 40

Author(s):

Michael Zeilinger ◽

Iryna M. Kurylyshyn ◽

Ulrich Häussermann ◽

Thomas F. Fässler

Keyword(s):

Phase Diagram ◽

High Temperature ◽

Single Crystal ◽

Structure Determination ◽

High Temperature Phase ◽

Temperature Phase ◽

X Ray

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ChemInform Abstract: High-Pressure Synthesis, Electron Energy-Loss Spectroscopy Investigations, and Single Crystal Structure Determination of a Spinel-Type Gallium Oxonitride Ga2.79□0.21(O3.05N0.76□0.19).

ChemInform ◽

10.1002/chin.200933005 ◽

2009 ◽

Vol 40 (33) ◽

Author(s):

Hubert Huppertz ◽

Stefanie A. Hering ◽

Carmen E. Zvoriste ◽

Stefan Lauterbach ◽

Oliver Oeckler ◽

...

Keyword(s):

Crystal Structure ◽

High Pressure ◽

Energy Loss ◽

Single Crystal ◽

Structure Determination ◽

Electron Energy Loss Spectroscopy ◽

Spinel Type ◽

Pressure Synthesis ◽

Electron Energy Loss

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Ultrasonic determination of single crystal sapphire fiber modulus

Journal of Nondestructive Evaluation ◽

10.1007/bf00735669 ◽

1995 ◽

Vol 14 (1) ◽

pp. 31-38 ◽

Cited By ~ 14

Author(s):

Haydn N. G. Wadley ◽

Yichi Lu ◽

Jeffrey A. Goldman

Keyword(s):

Single Crystal ◽

Ultrasonic Determination ◽

Single Crystal Sapphire ◽

Sapphire Fiber

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Single Crystal Growth of High-Pressure Phases of Ice and Salt Hydrate Far Below the Original Melting Point by Mixing Alcohol: Crystal Structure Determination of Magnesium Chloride Heptahydrate

10.26434/chemrxiv.11345063.v1 ◽

2019 ◽

Author(s):

Keishiro Yamashita ◽

Kazuki Komatsu ◽

Hiroyuki Kagi

Keyword(s):

Crystal Structure ◽

High Pressure ◽

Crystal Growth ◽

Single Crystal ◽

Room Temperature ◽

Growth Technique ◽

Salt Hydrate ◽

X Ray

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl2·7H2O at 2.51 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.

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