scholarly journals Effect of ultrasound on the kinetics of oxidation of octan-2-ol and other secondary alcohols with sodium bromate, mediated by ruthenium tetraoxide in a biphasic system

1995 ◽  
Vol 2 (1) ◽  
pp. S33-S38 ◽  
Author(s):  
Andrew Mills ◽  
Carolyn Holland
Keyword(s):  
Biphasic System ◽  
Secondary Alcohols ◽  
Kinetics Of Oxidation ◽  
Sodium Bromate ◽  
Kinetics Of ◽  
Ruthenium Tetraoxide

scholarly journals Oxidation of Some Aliphatic Alcohols by Pyridinium Chlorochromate -Kinetics and Mechanism

2009 ◽  
Vol 6 (1) ◽  
pp. 237-246 ◽  
Author(s):  
Sapana Jain ◽  
B. L. Hiran ◽  
C. V. Bhatt
Keyword(s):  
Dielectric Constant ◽  
Carbonyl Compounds ◽  
Activation Parameters ◽  
Dipole Interaction ◽  
Hydrogen Ion ◽  
Pyridinium Chlorochromate ◽  
Secondary Alcohols ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Kinetics Of

Kinetics of oxidation of some aliphatic primary and secondary alcoholsviz.,ethanol, propan-1-ol, propan-2-ol, butan-1-ol, butan-2-ol and 2-methyl butanol by pyridinium chlorochromate (PCC) have been studied in water- perchloric acid medium. The reaction shows first order dependence with respect to pyridinium chlorochromate [PCC] and hydrogen ion [H+]. The rate of oxidation decreases with increase in dielectric constant of solvent suggests ion-dipole interaction. Activation parameters have been evaluated. Products are carbonyl compounds and free radical absence was proved. A tentative mechanism has been proposed.

The kinetics of oxidation of secondary alcohols by N-chlorosuccinimide

1970 ◽  
Vol 11 (24) ◽  
pp. 2039-2042 ◽  
Author(s):  
N.S. Srinivasan ◽  
N. Venkatasubramanian
Keyword(s):  
Secondary Alcohols ◽  
Kinetics Of Oxidation ◽  
Kinetics Of

Spectrocoulometry – a new spectro-electrochemical technique

1987 ◽  
Vol 52 (6) ◽  
pp. 1386-1396 ◽  
Author(s):  
Ján Mocák ◽  
Michal Németh ◽  
Mieczyslaw Lapkowski ◽  
Jerzy W. Strojek
Keyword(s):  
Optical Probe ◽  
Optical Signal ◽  
Open Circuit ◽  
Electrochemical Technique ◽  
Kinetics Of Oxidation ◽  
Hydrolytic Reaction ◽  
Experimental Errors ◽  
Mechanism And Kinetics ◽  
Kinetics Of

A spectrocoulometric macrocell with a direct-view optical probe was designed and constructed, where the optical signal is transferred by light-conducting glass or quartz fibres permitting to work at wavelengths above 410 or 300 nm. The method of measurement on the proposed equipment is described; it was tested in the study of the mechanism and kinetics of oxidation of Fe(bipy)32+ ions (bipy = 2,2'-bipyridyl) with the use of potentiostatic coulometric electrolysis with open-circuit relaxation at a suitable time. The primary product of electrolysis, Fe(bipy)33+, undergoes a follow-up hydrolytic reaction with the formation of a binuclear complex. The rate constant of the reaction of the first order involves the contributions, kBi, from all bases present in solution; the corresponding values for H2O, OH-, bipy, and CH3COO- ions at a ionic strength 0·5 mol dm-3 and 25 °C were determined as kOH = (5·0 ± 0·6) . 105 mol-1 dm3 s-1, kbipy = (1·3 ± 0·2) . 10-1 mol-1 dm3 s-1, kAc = (5·8 ± 1·0) . 10-2 mol-1 dm3 s-1, and kH2O is not significant with respect to experimental errors.

Effects of salts on the kinetics of oxidation of alkenes by thallic salts in aqueous solutions

1981 ◽  
Vol 46 (3) ◽  
pp. 693-700 ◽  
Author(s):  
Milan Strašák ◽  
Jaroslav Majer
Keyword(s):  
Aqueous Solutions ◽  
Phase Transfer ◽  
Heterogeneous Reaction ◽  
Qualitative Model ◽  
Kinetic Effect ◽  
Tetraalkylammonium Salts ◽  
Reaction Conditions ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Heterogeneous Reaction Conditions

The kinetics of oxidation of alkenes by thallic sulphate in aqueous solutions, involving the two reaction steps-the hydroxythallation and the dethallation - was studied, and the effect of salts on the kinetics was examined; this made it possible to specify more precisely the reaction mechanism and to suggest a qualitative model of the reaction coordinate. It was found that in homogeneous as well as in heterogeneous reaction conditions, the reaction can be accelerated appreciably by adding tetraalkylammonium salts. These salts not only operate as catalysts of the phase transfer, but also exert a significant kinetic effect, which can be explained with a simplification in terms of a stabilization of the transition state of the reaction.

Kinetics of oxidation of ammonia on cobalt catalyst I model of the reactor with catalytically active wall

1982 ◽  
Vol 47 (8) ◽  
pp. 2087-2096 ◽  
Author(s):  
Bohumil Bernauer ◽  
Antonín Šimeček ◽  
Jan Vosolsobě
Keyword(s):  
Parabolic Equations ◽  
Cobalt Catalyst ◽  
Nonlinear Parabolic Equations ◽  
Catalytic Reactions ◽  
Temperature Profiles ◽  
Dimensional Model ◽  
Kinetics Of Oxidation ◽  
Nonlinear Parabolic ◽  
Catalytically Active ◽  
Kinetics Of

A two dimensional model of a tabular reactor with the catalytically active wall has been proposed in which several exothermic catalytic reactions take place. The derived dimensionless equations enable evaluation of concentration and temperature profiles on the surface of the active component. The resulting nonlinear parabolic equations have been solved by the method of orthogonal collocations.

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