LIGHT ELEMENT METASOMATISM OF THE CONTINENTAL MANTLE: THE EVIDENCE AND THE CONSEQUENCES

Author(s):  
F.E. LLOYD ◽  
D.K. BAILEY
Keyword(s):  
Author(s):  
G.F. Bastin ◽  
H.J.M. Heijligers ◽  
J.M. Dijkstra

For the calculation of X-ray intensities emitted by elements present in multi-layer systems it is vital to have an accurate knowledge of the x-ray ionization vs. mass-depth (ϕ(ρz)) curves as a function of accelerating voltage and atomic number of films and substrate. Once this knowledge is available the way is open to the analysis of thin films in which both the thicknesses as well as the compositions can usually be determined simultaneously.Our bulk matrix correction “PROZA” with its proven excellent performance for a wide variety of applications (e.g., ultra-light element analysis, extremes in accelerating voltage) has been used as the basis for the development of the software package discussed here. The PROZA program is based on our own modifications of the surface-centred Gaussian ϕ(ρz) model, originally introduced by Packwood and Brown. For its extension towards thin film applications it is required to know how the 4 Gaussian parameters α, β, γ and ϕ(o) for each element in each of the films are affected by the film thickness and the presence of other layers and the substrate.


Author(s):  
Nestor J. Zaluzec

The application of electron energy loss spectroscopy (EELS) to light element analysis is rapidly becoming an important aspect of the microcharacterization of solids in materials science, however relatively stringent requirements exist on the specimen thickness under which one can obtain EELS data due to the adverse effects of multiple inelastic scattering.1,2 This study was initiated to determine the limitations on quantitative analysis of EELS data due to specimen thickness.


Nature ◽  
1986 ◽  
Vol 323 (6084) ◽  
pp. 138-140 ◽  
Author(s):  
I. A. Franchi ◽  
I. P. Wright ◽  
C. T. Pillinger

1992 ◽  
Vol 7 (7) ◽  
pp. 881-887 ◽  
Author(s):  
G M Gusinskii ◽  
I V Kudryavtsev ◽  
V K Kudoyarova ◽  
V O Naidenov ◽  
L A Rassadin

2000 ◽  
Vol 72 (11) ◽  
pp. 2609-2612 ◽  
Author(s):  
Uwe Bergmann ◽  
Oliver C. Mullins ◽  
S. P. Cramer

2016 ◽  
Vol 55 (9) ◽  
pp. 095502
Author(s):  
Kuniyuki Sato ◽  
Atsushi Ogura ◽  
Haruhiko Ono

1994 ◽  
Vol 72 (11-12) ◽  
pp. 772-781 ◽  
Author(s):  
Michael M. Briley ◽  
Roger A. Bell ◽  
James E. Hesser ◽  
Graeme H. Smith

Abundance patterns of the elements C, N, and O are sensitive probes of stellar nucleosynthesis processes and, in addition, O abundances are an important input for stellar age determinations. Understanding the nature of the observed distribution of these elements is key to constraining protogalactic star formation history. Patterns deduced from low-resolution spectroscopy of the CN, CH, NH, and CO molecules for low-mass stars in their core-hydrogen or first shell-hydrogen burning phases in the oldest ensembles known, the Galactic globular star clusters, are reviewed. New results for faint stars in NGC 104 (47 Tuc, C0021-723) reveal that the bimodal, anticorrelated pattern of CN and CH strengths found among luminous evolved stars is also present in stars nearing the end of their main-sequence lifetimes. In the absence of known mechanisms to mix newly synthesized elements from the interior to the observable surface layers of such unevolved stars, those particular inhomogeneities imply that the original material from which the stars formed some 15 billion years ago was chemically inhomogeneous in the C and N elements. However, in other clusters, observations of abundance ratios and C isotope ratios suggest that alterations to surface chemical compositions are produced as stars evolve from the main sequence through the red giant branch. Thus, the current observed distributions of C, N, and O among the brightest stars (those also observed most often) may not reflect the true distribution from which the protocluster cloud formed. The picture that is emerging of the C, N, and O abundance patterns within globular clusters may be one which requires a complicated combination of stellar evolutionary and primordial effects for its explanation.


2000 ◽  
Vol 31 ◽  
pp. 765-766
Author(s):  
J. Osán ◽  
C.-U. Ro ◽  
I. Szalóki ◽  
A. Worobiec ◽  
J. De Hoog ◽  
...  

2011 ◽  
Vol 2 ◽  
pp. 394-404 ◽  
Author(s):  
Simon Kurasch ◽  
Jannik C Meyer ◽  
Daniela Künzel ◽  
Axel Groß ◽  
Ute Kaiser

The accuracy of multislice high-resolution transmission electron microscopy (HRTEM) simulation can be improved by calculating the scattering potential using density functional theory (DFT) Gemming, T.; Möbus, G.; Exner, M.; Ernst, F.; Rühle, M. J. Microsc. 1998, 190, 89–98. doi:10.1046/j.1365-2818.1998.3110863.xDeng, B.; Marks, L. D. Acta Crystallogr., Sect. A 2006, 62, 208–216. doi:10.1107/S010876730601004X. This approach accounts for the fact that electrons in the specimen are redistributed according to their local chemical environment. This influences the scattering process and alters the absolute and relative contrast in the final image. For light element materials with well defined geometry, such as graphene and hexagonal boron nitride monolayers, the DFT based simulation scheme turned out to be necessary to prevent misinterpretation of weak signals, such as the identification of nitrogen substitutions in a graphene network. Furthermore, this implies that the HRTEM image does not only contain structural information (atom positions and atomic numbers). Instead, information on the electron charge distribution can be gained in addition. In order to produce meaningful results, the new input parameters need to be chosen carefully. Here we present details of the simulation process and discuss the influence of the main parameters on the final result. Furthermore we apply the simulation scheme to three model systems: A single atom boron and a single atom oxygen substitution in graphene and an oxygen adatom on graphene.


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