High temperature electrochemical production of hydrogen

Author(s):  
Vanja Subotić ◽  
Christoph Hochenauer
Author(s):  
Kee-Nam Song ◽  
Sung-Deok Hong ◽  
Hong-Yoon Park

PHE (Process Heat Exchanger) is a key component in transferring the high temperature heat generated from a VHTR (Very High Temperature Reactor) to the chemical reaction for massive production of hydrogen. A performance test on a small-scale PHE prototype made of Hastelloy-X is currently undergoing in a small-scale gas loop at the Korea Atomic Energy Research Institute. Previous researches on the high-temperature structural analysis of the small-scale PHE prototype had been performed using parent material properties over the whole region. In this study, high-temperature elastic structural analysis considering mechanical properties in the weld zone was performed and the analysis result was compared with previous researches.


2020 ◽  
Vol 7 (8) ◽  
pp. 1360-1366 ◽  
Author(s):  
Xuan Zhao ◽  
Yu Wang ◽  
Yunli Da ◽  
Xinxia Wang ◽  
Tingting Wang ◽  
...  

Abstract The two-electron reduction of molecular oxygen represents an effective strategy to enable the green, mild and on-demand synthesis of hydrogen peroxide. Its practical viability, however, hinges on the development of advanced electrocatalysts, preferably composed of non-precious elements, to selectively expedite this reaction, particularly in acidic medium. Our study here introduces 2H-MoTe2 for the first time as the efficient non-precious-metal-based electrocatalyst for the electrochemical production of hydrogen peroxide in acids. We show that exfoliated 2H-MoTe2 nanoflakes have high activity (onset overpotential ∼140 mV and large mass activity of 27 A g−1 at 0.4 V versus reversible hydrogen electrode), great selectivity (H2O2 percentage up to 93%) and decent stability in 0.5 M H2SO4. Theoretical simulations evidence that the high activity and selectivity of 2H-MoTe2 arise from the proper binding energies of HOO* and O* at its zigzag edges that jointly favor the two-electron reduction instead of the four-electron reduction of molecular oxygen.


Author(s):  
K.V. Simeiko ◽  
B.K. Ilienko ◽  
M.A. Sidorenko

When implementing a number of high-temperature processes with heat supply to the reaction zone (allothermic processes), it is impossible or economically inexpedient the burning of fossil fuels to achieve the required temperature level. The possibilities of these processes implementation through the use of electrothermal fluidized bed (ETFB) techniques are considered. Such processes include, for example, the production of hydrogen by the pyrolysis of hydrocarbon gases, the production of silicon carbide and other carbides, the production of artificial graphite and the thermal purification of natural graphite, the high-temperature heating of gases and gas mixtures. These processes can be carried out in the temperature range of 600–3000 °С using fine-dispersed materials or directly in the gas phase using ETFB. In a number of processes ETFB technology can be applied as a source of high temperature gas production, used either for the implementation of this technological process, or for ensuring the operation of technological or heat engineering equipment. Also considered the main structural characteristics of the equipment that ensure the implementation of processes in the ETPS. Bibl. 37.


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