scholarly journals Morphological stability of spherical particles - Extension of the Mullins-Sekerka criteria to multi-component alloys under a non-stationary diffusive regime

2021 ◽  
Vol 205 ◽  
pp. 116539
Author(s):  
Gildas Guillemot ◽  
Charles-André Gandin
2020 ◽  
pp. 1-18
Author(s):  
Sönke Maus

Abstract Columnar sea ice grows with an interface of tiny parallel ice plates, the distance of which is known as plate spacing. While it has been proposed as a fundamental microstructure scale of sea ice, the physics behind its formation has not been fully understood. Here the problem is analysed on the basis of morphological stability theory to propose a model that results in a physically consistent prediction of the relationship between the plate spacing a0 and growth velocity V. The relationship may be divided into two regimes. In the diffusive regime, for V above ≈2 × 10−4 cm s−1 one finds a0 ~ V−2/3 to first order. In the convective regime, the extent of diffusive boundary layer is controlled by solutal convection near the interface, which leads to the proportionality a0 ~ V−1/3. From a comparison to observations it is evident that the plate spacing is predictable over 5 orders of magnitude in the growth velocity, covering the range from fast laboratory ice growth to slow accretion at the bottom of marine ice shelves. The predictability opens new paths towards concise modelling of marine and sea-ice microstructure and physical properties.


Author(s):  
Daniel UGARTE

Small particles exhibit chemical and physical behaviors substantially different from bulk materials. This is due to the fact that boundary conditions can induce specific constraints on the observed properties. As an example, energy loss experiments carried out in an analytical electron microscope, constitute a powerful technique to investigate the excitation of collective surface modes (plasmons), which are modified in a limited size medium. In this work a STEM VG HB501 has been used to study the low energy loss spectrum (1-40 eV) of silicon spherical particles [1], and the spatial localization of the different modes has been analyzed through digitally acquired energy filtered images. This material and its oxides have been extensively studied and are very well characterized, because of their applications in microelectronics. These particles are thus ideal objects to test the validity of theories developed up to now.Typical EELS spectra in the low loss region are shown in fig. 2 and energy filtered images for the main spectral features in fig. 3.


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