In the probe limit, we study the holographic p-wave phase transition in the Gauss–Bonnet gravity via numerical and analytical methods. Concretely, we study the influences of the external magnetic field on the Maxwell complex vector model in the five-dimensional Gauss–Bonnet–AdS black hole and soliton backgrounds, respectively. For the two backgrounds, the results show that the magnetic field enhances the superconductor phase transition in the case of the lowest Landau level, while the increasing Gauss–Bonnet parameter always hinders the vector condensate. Moreover, the Maxwell complex vector model is a generalization of the SU(2) Yang–Mills model all the time. In addition, the analytical results backup the numerical results. Furthermore, this model might provide a holographic realization for the QCD vacuum instability.