Insight into the mode of action of Pd-doped zero-valent iron nanoparticles @graphene (Pd/FePs@G) toward carbon tetrachloride dechlorination reaction in aqueous solution

2018 ◽  
Vol 560 ◽  
pp. 84-93 ◽  
Author(s):  
Yiyang Ma ◽  
Yeyao Wang ◽  
Xiaofan Lv ◽  
Fansheng Meng ◽  
Qi Yang
Keyword(s):  
Aqueous Solution ◽  
Carbon Tetrachloride ◽  
Mode Of Action ◽  
Iron Nanoparticles ◽  
Zero Valent Iron ◽  
Zero Valent Iron Nanoparticles ◽  
Insight Into ◽  
Dechlorination Reaction

Perchlorate degradation in aqueous solution using chitosan-stabilized zero-valent iron nanoparticles

2016 ◽  
Vol 171 ◽  
pp. 164-173 ◽  
Author(s):  
Yanhua Xie ◽  
Yan Yi ◽  
Yinhong Qin ◽  
Lanting Wang ◽  
Guoming Liu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Iron Nanoparticles ◽  
Zero Valent Iron ◽  
Zero Valent Iron Nanoparticles

Zero-valent iron nanoparticles with sustained high reductive activity for carbon tetrachloride dechlorination

RSC Advances ◽  
2015 ◽  
Vol 5 (67) ◽  
pp. 54497-54504 ◽  
Author(s):  
Ying-Chao Huo ◽  
Wen-Wei Li ◽  
Di Min ◽  
Dan-Dan Wang ◽  
Hou-Qi Liu ◽  
...  
Keyword(s):  
Carbon Tetrachloride ◽  
Iron Nanoparticles ◽  
Zero Valent Iron ◽  
Oxide Shell ◽  
Fe Oxide ◽  
Zero Valent Iron Nanoparticles

Fe oxide shell breakdown and new oxyhydroxide formation during CT dechlorination contribute to pH self-buffering and sustained nZVI reactivity.

scholarly journals Reductive Dechlorination of Chloroacetamides with NaBH4 Catalyzed by Zero Valent Iron, ZVI, Nanoparticles in ORMOSIL Matrices Prepared via the Sol-Gel Route

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 986
Author(s):  
Michael Meistelman ◽  
Dan Meyerstein ◽  
Amos Bardea ◽  
Ariela Burg ◽  
Dror Shamir ◽  
...  
Keyword(s):  
Reductive Dechlorination ◽  
Sol Gel ◽  
Reaction Medium ◽  
Zero Valent Iron ◽  
Catalyst Structure ◽  
Organically Modified ◽  
Plausible Mechanism ◽  
Zero Valent Iron Nanoparticles ◽  
Insight Into ◽  
Dechlorination Reaction

The efficient reductive dechlorination, as remediation of dichloroacetamide and monochloroacetamide, toxic and abundant pollutants, using sodium borohydride catalyzed by zero valent iron nanoparticles (ZVI-NPs), entrapped in organically modified hybrid silica matrices prepared via the sol-gel route, ZVI@ORMOSIL, is demonstrated. The results indicate that the extent of the dechlorination reaction depends on the nature of the substrate and on the reaction medium. By varying the amount of catalyst or reductant in the reaction it was possible to obtain conditions for full dechlorination of these pollutants to nontoxic acetamide and acetic acid. A plausible mechanism of the catalytic process is discussed. The present work expands the scope of ZVI-NP catalyzed reduction of polluting compounds, first reports the catalytic parameters of chloroacetamide reduction, and offers additional insight into the heterogeneous catalyst structure of M0@ORMOSIL sol-gel. The ZVI@ORMOSIL catalyst is ferromagnetic and hence can be recycled easily.

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