Characterization and degradation of a polyaryl ether based superplasticizer for use in concrete barriers in deep geological repositories

2018 ◽  
Vol 95 ◽  
pp. 172-181 ◽  
Author(s):  
Alexander N. Chernyshev ◽  
Mats Jonsson ◽  
Kerstin Forsberg
Author(s):  
Mehdi Hosseinpour ◽  
Kirolos Haleem

Road departure (RD) crashes are among the most severe crashes that can result in fatal or serious injuries, especially when involving large trucks. Most previous studies neglected to incorporate both roadside and median hazards into large-truck RD crash severity analysis. The objective of this study was to identify the significant factors affecting driver injury severity in single-vehicle RD crashes involving large trucks. A random-parameters ordered probit (RPOP) model was developed using extensive crash data collected on roadways in the state of Kentucky between 2015 and 2019. The RPOP model results showed that the effect of local roadways, the natural logarithm of annual average daily traffic (AADT), the presence of median concrete barriers, cable barrier-involved collisions, and dry surfaces were found to be random across the crash observations. The results also showed that older drivers, ejected drivers, and drivers trapped in their truck were more likely to sustain severe single-vehicle RD crashes. Other variables increasing the probability of driver injury severity have included rural areas, dry road surfaces, higher speed limits, single-unit truck types, principal arterials, overturning-consequences, truck fire occurrence, segments with median concrete barriers, and roadside fixed object strikes. On the other hand, wearing seatbelt, local roads and minor collectors, higher AADT, and hitting median cable barriers were associated with lower injury severities. Potential safety countermeasures from the study findings include installing median cable barriers and flattening steep roadside embankments along those roadway stretches with high history of RD large-truck-related crashes.


1992 ◽  
Vol 294 ◽  
Author(s):  
Craig A. Dicke ◽  
Robert W. Smith

ABSTRACTConcrete is a major component in many low-level radioactive waste (LLW) disposal facilities. The use of concrete is widespread because of its physical and structural properties and because it provides geochemical control on metal and radionuclide releases. Organic compounds are often disposed with radionuclides in LLW disposal facilities. Interactions between radionuclides and chelating agents must be evaluated to estimate mobility of radionuclides in concrete vaults. This paper quantifies the effects of two common organic components [citric acid and ethylenediaminetetraacetic acid (EDTA)] on radionuclide mobility in concrete barriers by using equilibrium geochemical calculations.Equilibrium speciation calculations indicate that some radionuclides are chelated in groundwater (pH 7) but are destabilized in the highly alkaline (pH 13) concrete pore fluids. Radionuclides complexed by EDTA and citrate are replaced by calcium in the concrete pore fluids. In addition, the citrate nuclide complex reacts to form uncomplexed citrate in concrete pore fluids. The chemical performance of concrete LLW disposal facilities should not be compromised by small amounts of chelating agents disposed with some radionuclides. However, EDTA may form significant nickel and cobalt complexes above the pH important in the long-term service life of concrete barriers.


Author(s):  
Scott K. Rosenbaugh ◽  
Ronald K. Faller ◽  
Jennifer D. Schmidt ◽  
Robert W. Bielenberg

Roadway resurfacing and overlay projects effectively reduce the height of roadside barriers placed adjacent to the roadway, which can negatively affect their crashworthiness. More recently, bridge rails and concrete barriers have been installed with slightly increased heights to account for future overlays. However, adjacent guardrails and approach transitions have not yet been modified to account for overlays. The objective of this project was to develop an increased-height approach guardrail transition (AGT) to be crashworthy both before and after roadway overlays of up to 3 in. The 34-in. tall, thrie-beam transition detailed here was designed such that the system would be at its nominal 31-in. height following a 3-in. roadway overlay. Additionally, the upstream end of the AGT incorporated a symmetric W-to-thrie transition segment that would be replaced by an asymmetric transition segment after an overlay to keep the W-beam guardrail upstream from the transition at its nominal 31-in. height. The 34-in. tall AGT was connected to a modified version of the standardized buttress to mitigate the risk of vehicle snag below the rail. The barrier system was evaluated through two full-scale crash tests in accordance with Test Level 3 (TL-3) of AASHTO’s Manual for Assessing Safety Hardware (MASH) and satisfied all safety performance criteria. Thus, the 34-in. tall AGT with modified transition buttress was determined to be crashworthy to MASH TL-3 standards. Finally, implementation guidance was provided for the 34-in. tall AGT and its crashworthy variations.


MRS Bulletin ◽  
1994 ◽  
Vol 19 (5) ◽  
pp. 32-38 ◽  
Author(s):  
Po-zen Wong

Porous media represent a broad class of mesoscopically disordered materials that are important in many industrial processes, mostly involving the transport of fluids. For examples, the flow of oil and water in sedimentary rock determines the producibility of oil reservoirs; diffusion and dispersion of molecules in soil govern the spreading of both fertilizers and contaminants; chemical reactors use porous catalysts to enhance the mixing of reagents; the containment of chemical and nuclear wastes depends on the low permeability of concrete barriers. These are just a few problems familiar to our everyday lives. The study of porous media has traditionally been under the disciplines of chemical, mechanical, and petroleum engineering. Only in recent years has the field begun to attract the interest of physicists. The displacement of one fluid by another in a porous medium is now recognized as one of the archetypal systems for studying the physics of pattern formation and interface growth. Fluids transport is known to involve effects due to the microgeometry of the pores, the connectivity of the pore network, and the wetting properties of the pore surfaces. These are all fundamental scientific issues that require the understanding of the physics and chemistry associated with the porous materials. Tackling these problems requires the collaboration of scientists from many different disciplines. Although much work has been done and a great deal has been learned, many interesting and important issues remain. In an article written five years ago, I gave a pedagogical overview of some of the problems in porous media that captivated my own interest.


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