Numerical Modeling of the Effects of Pore Characteristics on the Electric Breakdown of Rock for Plasma Pulse Geo Drilling

Drilling costs can be 80% of geothermal project investment, so decreasing these deep drilling costs substantially reduces overall project costs, contributing to less expensive geothermal electricity or heat generation. Plasma Pulse Geo Drilling (PPGD) is a contactless drilling technique that uses high-voltage pulses to fracture the rock without mechanical abrasion, which may reduce drilling costs by up to 90% of conventional mechanical rotary drilling costs. However, further development of PPGD requires a better understanding of the underlying fundamental physics, specifically the dielectric breakdown of rocks with pore fluids subjected to high-voltage pulses. This paper presents a numerical model to investigate the effects of the pore characteristics (i.e., pore fluid, shape, size, and pressure) on the occurrence of the local electric breakdown (i.e., plasma formation in the pore fluid) inside the granite pores and thus on PPGD efficiency. Investigated are: (i) two pore fluids, consisting of air (gas) or liquid water; (ii) three pore shapes, i.e., ellipses, circles, and squares; (iii) pore sizes ranging from 10 to 150 μm; (iv) pore pressures ranging from 0.1 to 2.5 MPa. The study shows how the investigated pore characteristics affect the local electric breakdown and, consequently, the PPGD process.

Taphonomic and Diagenetic Pathways to Protein Preservation, Part I: The Case of Tyrannosaurus rex Specimen MOR 1125

Many recent reports have demonstrated remarkable preservation of proteins in fossil bones dating back to the Permian. However, preservation mechanisms that foster the long-term stability of biomolecules and the taphonomic circumstances facilitating them remain largely unexplored. To address this, we examined the taphonomic and geochemical history of Tyrannosaurus rex specimen Museum of the Rockies (MOR) 1125, whose right femur and tibiae were previously shown to retain still-soft tissues and endogenous proteins. By combining taphonomic insights with trace element compositional data, we reconstruct the postmortem history of this famous specimen. Our data show that following prolonged, subaqueous decay in an estuarine channel, MOR 1125 was buried in a coarse sandstone wherein its bones fossilized while interacting with oxic and potentially brackish early-diagenetic groundwaters. Once its bones became stable fossils, they experienced minimal further chemical alteration. Comparisons with other recent studies reveal that oxidizing early-diagenetic microenvironments and diagenetic circumstances which restrict exposure to percolating pore fluids elevate biomolecular preservation potential by promoting molecular condensation reactions and hindering chemical alteration, respectively. Avoiding protracted interactions with late-diagenetic pore fluids is also likely crucial. Similar studies must be conducted on fossil bones preserved under diverse paleoenvironmental and diagenetic contexts to fully elucidate molecular preservation pathways.

Experimental Study on Petrophysical Properties as a Tool to Identify Pore Fluids in Tight-Rock Reservoirs

The petrophysical properties can be proper indicators to identify oil and gas reservoirs, since the pore fluids have significant effects on the wave response. We have performed ultrasonic measurements on two sets of tight siltstones and dolomites at partial saturation. P- and S-wave velocities are obtained by the pulse transmission technique, while attenuation is calculated using the centroid-frequency shift and spectral-ratio methods. The fluid sensitivities of different properties (i.e., P- and S-wave velocities, impedances and attenuation, Poisson's ratio, density, and their combinations) are quantitatively analyzed by considering the data distribution, based on the crossplot technique. The result shows that the properties (P- to S-wave velocity and attenuation ratios, Poisson's ratio, and first to second Lamé constant ratio) with high fluid-sensitivity indicators successfully distinguish gas from oil and water, unlike oil from water. Moreover, siltstones and dolomites can be identified on the basis of data distribution areas. Ultrasonic rock-physics templates of the P- to S-wave velocity ratio vs. the product of first Lamé constant with density obtained with a poroelastic model, considering the structural heterogeneity and patchy saturation, are used to predict the saturation and porosity, which are in good agreement with the experimental data at different porosity ranges.

The Carbon-Sulfur Link in the Remineralization of Organic Carbon in Surface Sediments

Here we present the carbon isotopic composition of dissolved inorganic carbon (DIC) and the sulfur isotopic composition of sulfate, along with changes in sulfate concentrations, of the pore fluid collected from a series of sediment cores located along a depth transect on the Iberian Margin. We use these data to explore the coupling of microbial sulfate reduction (MSR) to organic carbon oxidation in the uppermost (up to nine meters) sediment. We argue that the combined use of the carbon and sulfur isotopic composition, of DIC and sulfate respectively, in sedimentary pore fluids, viewed through a δ13CDIC vs. δ34SSO4 cross plot, reveals significant insight into the nature of carbon-sulfur coupling in marine sedimentary pore fluids on continental margins. Our data show systemic changes in the carbon and sulfur isotopic composition of DIC and sulfate (respectively) where, at all sites, the carbon isotopic composition of the DIC decreases before the sulfur isotopic composition of sulfate increases. We compare our results to global data and show that this behavior persists over a range of sediment types, locations and water depths. We use a reactive-transport model to show how changes in the amount of DIC in seawater, the carbon isotopic composition of organic matter, the amount of organic carbon oxidation by early diagenetic reactions, and the presence and source of methane influence the carbon and sulfur isotopic composition of sedimentary pore fluids and the shape of the δ13CDIC vs. δ34SSO4 cross plot. The δ13C of the DIC released during sulfate reduction and sulfate-driven anaerobic oxidation of methane is a major control on the minimum δ13CDIC value in the δ13CDIC vs. δ34SSO4 cross plot, with the δ13C of the organic carbon being important during both MSR and combined sulfate reduction, sulfate-driven AOM and methanogenesis.

Dilatancy stabilises shear failure in rock

<p>Failure and fault slip in crystalline rocks is associated with dilation. When pore fluids are present and drainage is insufficient, dilation leads to pore pressure drops, which in turn lead to strengthening of the material. We conducted laboratory rock fracture experiments with direct in-situ fluid pressure measurements which demonstrate that dynamic rupture propagation and fault slip can be stabilised (i.e., become quasi-static) by such a dilatancy strengthening effect. We also observe that, for the same effective pressures but lower pore fluid pressures, the stabilisation process may be arrested when the pore fluid pressure approaches zero and vaporises, resulting in dynamic shear failure. In case of a stable rupture, we witness continued after slip after the main failure event that is the result of pore pressure recharge of the fault zone. All our observations are quantitatively explained by a simple spring-slider model combining slip-weakening behaviour, slip-induced dilation, and pore fluid diffusion. Using our data in an inverse problem, we estimate the key parameters controlling rupture stabilisation, fault dilation rate and fault zone storage. These estimates are used to make predictions for the pore pressure drop associated with faulting, and where in the crust we may expect dilatancy stabilisation or vaporisation during earthquakes. For intact rock and well consolidated faults, we expect strong dilatancy strengthening between 4 and 6 km depth regardless of ambient pore pressure, and at greater depths when the ambient pore pressure approaches lithostatic pressure. In the uppermost part of the crust (<4 km), we predict vaporisation of pore fluids that eliminates dilatancy strengthening. The depth estimates where dilatant stabilisation is most likely coincide with geothermal energy reservoirs in crystalline rock (typically between 2 and 5 km depth) and in regions  where slow slip events are observed (pore pressure that approaches lithostatic pressure). </p>