Formation of Ag2, Au2 and AgAu particles on MgO(100): DFT study on the role of support-induced charge transfer in metal–metal interactions

2009 ◽  
Vol 255 (16) ◽  
pp. 7380-7384 ◽  
Author(s):  
Silvia A. Fuente ◽  
Patricia G. Belelli ◽  
María M. Branda ◽  
Ricardo M. Ferullo ◽  
Norberto J. Castellani
Keyword(s):  
Charge Transfer ◽  
Dft Study ◽  
Metal Interactions ◽  
Metal Metal ◽  
Induced Charge

Proton-induced collision dynamics on potential prebiotic sulfur species

2018 ◽  
Vol 20 (14) ◽  
pp. 9084-9089 ◽  
Author(s):  
Marie-Christine Bacchus-Montabonel
Keyword(s):  
Charge Transfer ◽  
Ab Initio ◽  
Theoretical Study ◽  
Collision Dynamics ◽  
Sulfur Species ◽  
Hcn Oligomers ◽  
Induced Charge

The role of sulfur in proton-induced charge transfer is analyzed through an ab initio theoretical study of mercaptoacetonitrile HSCH2CN with related HCN oligomers.

Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

2021 ◽  
Author(s):  
Aleksandra V. Paderina ◽  
Igor O Koshevoy ◽  
Elena V. Grachova
Keyword(s):  
Optical Properties ◽  
Metal Complexes ◽  
Crucial Role ◽  
Phosphine Ligands ◽  
Bridging Ligands ◽  
Coinage Metal ◽  
Metal Interactions ◽  
Metal Metal ◽  
State 1

The copper subgroup metal ions in the oxidation state +1 are classical candidates for the aggregation via non-covalent metal–metal interactions, which are supported by a number of the bridging ligands....

scholarly journals Self-assembly of alkynylplatinum(II) terpyridine amphiphiles into nanostructures via steric control and metal–metal interactions

2016 ◽  
Vol 113 (11) ◽  
pp. 2845-2850 ◽  
Author(s):  
Sammual Yu-Lut Leung ◽  
Keith Man-Chung Wong ◽  
Vivian Wing-Wah Yam
Keyword(s):  
Self Assembly ◽  
Phenylene Ethynylene ◽  
Temperature Dependent ◽  
Visible Absorption ◽  
Metal Interactions ◽  
Assembly Mechanism ◽  
Metal Metal ◽  
End Capping ◽  
Supramolecular Polymerization

A series of mono- and dinuclear alkynylplatinum(II) terpyridine complexes containing the hydrophilic oligo(para-phenylene ethynylene) with two 3,6,9-trioxadec-1-yloxy chains was designed and synthesized. The mononuclear alkynylplatinum(II) terpyridine complex was found to display a very strong tendency toward the formation of supramolecular structures. Interestingly, additional end-capping with another platinum(II) terpyridine moiety of various steric bulk at the terminal alkyne would lead to the formation of nanotubes or helical ribbons. These desirable nanostructures were found to be governed by the steric bulk on the platinum(II) terpyridine moieties, which modulates the directional metal−metal interactions and controls the formation of nanotubes or helical ribbons. Detailed analysis of temperature-dependent UV-visible absorption spectra of the nanostructured tubular aggregates also provided insights into the assembly mechanism and showed the role of metal−metal interactions in the cooperative supramolecular polymerization of the amphiphilic platinum(II) complexes.

Model potential study of non-valence correlation-bound anions of (C60)n clusters: the role of electric field-induced charge transfer

2019 ◽  
Vol 217 ◽  
pp. 547-560 ◽  
Author(s):  
Tae Hoon Choi ◽  
Kenneth D. Jordan
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Model Potential ◽  
Potential Study ◽  
Induced Charge

Orbitals associated with the non-valence correlation-bound anions of the C60 dimer and linear trimer from calculations allowing charge transfer.

Sign in / Sign up

Export Citation Format

Share Document