This chapter explains the implication of South Africa's transport fuel 2% blending. Using dry grain sorghum as feedstock with guaranteed food security has lower emission of 24.93kg/ha with emerging farmers who constituted 30% of the suppliers with a 3-year payback period. Using irrigated sorghum with food security as a priority has a relatively lower emission level of 11.47kg/ha from emerging farmers with a 9-year payback period. Using sugar beet has lower emission level of 0.12kg/ha with emerging farmers and a 3-year payback period. Soil organic content has significant influence on emissions from land use practices. Commercial sugar beet ethanol production caused high emission (4.84kg/ha) but has a short payback period of only 2 years which enhanced household food consumption by 12.5% and 31.50% under food security not a priority and food security as a priority, respectively. In all, grain sorghum food and beverage gross domestic product (GDP) increased, respectively, by 8%, 0.19%, and 0.23% under food security as not a priority, and increased by 20.83%, 0.44%, and 0.61% in opposite scenario, respectively.