Coupling Relationship between Lithofacies and Brittleness of the Shale Oil Reservoir: A Case Study of the Shahejie Formation in the Raoyang Sag

Analyzing the characteristics of rock brittleness in low-permeability mudstone and shale (MS) formations is imperative for efficient hydraulic fracturing stimulation. Rock brittleness depends on the mineral composition, organic matter abundance, and bedding structure. Based on the MS from Shahejie Formation mineral composition (clay mineral, felsic mineral, and calcareous mineral contents), total organic content, and bedding structure (laminated, laminar, and massive), six types of lithofacies were identified: clay-rich MS, felsic-rich MS, calcareous-rich MS, clay MS, felsic MS, and calcareous MS. The quartz, feldspar, calcite, and dolomite of the Shahejie Formation are brittle minerals. Consequently, lithofacies with high felsic and calcareous mineral contents are more brittle. In addition, laminated and laminar MS are also conducive to hydraulic fracturing. Therefore, laminated, organic-rich, and calcareous-rich MS are the dominant lithofacies for hydraulic fracturing in the Shahejie Formation. The lithofacies and brittleness index were predicted by the response characteristics between mineral compositions and logging curves. The 3521–3552 m section of well B11x is dominated by calcareous-rich MS with developed laminae, representing a favorable section for hydraulic fracturing. Fragile minerals and oil are widely developed in the lower part of the lower 1st member of the Shahejie Formation (Es1L) in the southwestern part of Zhaohuangzhuang-Suning, where hydraulic fracturing can be used to increase shale oil production.

Reuse of Wasted Bread as Soil Amendment: Bioprocessing, Effects on Alkaline Soil and Escarole (Cichorium endivia) Production

: In an era characterized by land degradation, climate change, and a growing population, ensuring high-yield productions with limited resources is of utmost importance. In this context, the use of novel soil amendments and the exploitation of plant growth-promoting microorganisms potential are considered promising tools for developing a more sustainable primary production. This study aimed at investigating the potential of bread, which represents a large portion of the global food waste, to be used as an organic soil amendment. A bioprocessed wasted bread, obtained by an enzymatic treatment coupled with fermentation, together with unprocessed wasted bread were used as amendments in a pot trial. An integrated analytical plan aimed at assessing i) the modification of the physicochemical properties of a typical Mediterranean alkaline agricultural soil, and ii) the plant growth-promoting effect on escarole (Cichorium endivia var. Cuartana), used as indicator crop, was carried out. Compared to the unamended soils, the use of biomasses raised the soil organic content (up to 37%) and total nitrogen content (up to 40%). Moreover, the lower pH and the higher organic acid content, especially in bioprocessed wasted bread, determined a major availability of Mn, Fe, and Cu in amended soils. The escaroles from pots amended with raw and bioprocessed bread had a number of leaves, 1.7- and 1.4-fold higher than plants cultivated on unamended pots, respectively, showing no apparent phytotoxicity and thus confirming the possible re-utilization of such residual biomasses as agriculture amendments.

Biophotocatalytic Reduction of CO2 in Anaerobic Biogas Produced from Wastewater Treatment Using an Integrated System

This study presents the bio-photocatalytic upgrading of biogas utilising carbon dioxide (CO2) as a potential option for beginning fossil fuel depletion and the associated environmental risks in the pursuit of sustainable development. Herein, magnetite photocatalyst (Fe-TiO2) was employed with an integrated anaerobic-photomagnetic system for the decontamination of municipality wastewater for biogas production. The Fe-TiO2 photocatalyst used, manufactured via a co-precipitation technique, had a specific surface area of 62.73 m2/g, micropore volume of 0.017 cm3/g and pore size of 1.337 nm. The results showed that using the ultraviolet-visible (UV-Vis) photomagnetic system as a post-treatment to the anaerobic digestion (AD) process was very effective with over 85% reduction in colour, chemical oxygen demand (COD) and turbidity. With an organic loading rate (OLR) of 0.394 kg COD/L·d and hydraulic retention time (HTR) of 21 days, a 92% degradation of the organic content (1.64 kgCOD/L) was attained. This maximised the bioenergy production to 5.52 kWh/m3 with over 10% excess energy to offset the energy demand of the UV-Vis lamp. Assuming 33% of the bioenergy produced was used as electricity to power the UV-Vis lamp, the CO2 emission reduction was 1.74 kg CO2 e/m3, with good potential for environmental conservation.

Removal of Excessive Nitrogen and Phosphorus from Urban Wastewater Using Local Microalgal Bloom

The organic content from urban wastewater is treated with various conventional processes efficiently. However, for biological treatment of secondary effluent containing excessive inorganic nitrogen and phosphorus, microalgae can be used. In this study, algal strains have been collected from locally available natural blooms and cultured in a BG-11 medium. Spirulina sp., the blue-green algae, dominant over the other species within the natural bloom, is applied in ten different dosages (0.2-2.5 g/L) to the synthetic wastewater with a 3-day hydraulic retention time. The removal efficiency of nitrate, ammonia, and phosphate have been observed to be about 60%, 30%, and 54% respectively. The highest removal efficiency has been found at 2.5 g/L of microalgae dose. Linear forms of Langmuir and Freundlich isotherms have been used for biosorption modeling, and both isotherms fit well with R2>60% and NRMSE<11% in all cases. Additionally, the separation factor and the adsorption intensity represent the favorability of the biosorption process. Journal of Engineering Science 12(3), 2021, 19-27

PHYSICAL AND ENGINEERING PROPERTIES OF PEAT SOIL STABILIZED WITH THE ADMIXTURE OF CACO3+RICE HUSK ASH DUE TO WATER INFILTRATION FROM SURROUNDING AREAS

Peat is a type of soil with high organic content, very low bearing capacity, and high uneven settlement. Some methods to improve soil have been applied to peat in order to make it strong enough for civilization-building foundation situated on it. Peat stabilization is a method that is continuously developed considering that the cost it needs is lower and this approach is more environmentally friendly compared to other methods. The admixture of lime (CaCO3) and Rice husk ash, a new ecofriendly stabilizer material, has been applied to peat soil and showed a good result. However, in studies conducted previously, the effect of water infiltration from surrounding areas of soil was stabilized was not involved as variable influencing the change of parameter. Based on that, this laboratory study was carried out to model the real condition in the field when the stabilization is performed and to identify the physical and engineering changes of peat soil in the 10th, 20th, and 30th days of stabilization in its border and middle parts, with the percentage of material stabilizer 5%, 10%, 15% and 20% of the unit weight of the initial condition of peat. The result of laboratory test shows that the addition of admixture of lime (CaCO3) and rice husk ash can improve the physical and engineering properties of peat soil are stabilized. Water infiltration occurred on peat soil is stabilized has not affected the physical and engineering properties of the soil. It can be seen from the physical and engineering properties of the border and central parts of peat soil is stabilized that still have a similar value. It is assumed to be caused by CaSiO3 gel formed still needs a longer duration to become stable gel. However, in this initial study it was known that the more stabilizers added, made the better the parameters of the stabilized peat soil.

Addition of Tithonia Compost and Lime as Ultisol Soil Fertility Improvement for Oil Palm Sedling Media

Research to improve soil fertility, especially the chemical characteristics of Ultisol, has been carried out by adding compost and lime. The incubation method of soil plus compost at a dose of 0.5 kg/pot – 2 kg/pot and 1x exchanged Al lime was carried out for 2 weeks. The results of soil nutrient analysis after incubation were an increase in pH of 0.58 points, a decrease in exchanged Al to unmeasured, an increase in the C-organic content of the soil by 3.44%, an increase in the total N-value of the soil by 0.19%, an increase in the amount of soil organic matter. P-available was 5.81 ppm and exchanged K soil increased by 0.02 me/100 g soil. Likewise, the micro elements analyzed also increase. Thus there is a change in the chemical properties of the soil towards the better. The increase in nutrients N, P, K, Ca, and Mg clearly comes from tithonia, which is the result of decomposition of tithonia compost which is added containing high nutrients. In addition, tithonia compost produces organic acids that can dissolve previously insoluble nutrients into soluble ones. The improvement of the chemical properties of the soil towards a better direction is expected to be able to increase the growth of oil palm seedlings planted on the seedling medium growing.

The Potential of Paper Industry Sludge Potency as Organic Soil Amandment

Sludge from the paper industry can affect soil fertility due to its organic content. However, sludge as waste has a contamination risk of polluting the soil. This research focused on the chemical properties content of sludge from the paper industry (pH, organic C, macro and micronutrients, heavy metals) and contaminant microbes (E. coli and Salmonella sp.) in order to evaluate to the potency of sludge to be soil amendment. Sludge sample was taken in 0-20 cm depth from Sumengko Village, Wringinanom, Gresik. The chemical properties were measured in Soil Chemistry Laboratory in Soil Science Department, and the biological properties were measured in Pest and Disease Laboratory in the Agricultural Faculty of Brawijaya University. The chemical and biological properties of sludge were compared to quality standards according to Keputusan Menteri Pertanian No. 261/2019 (Kepmentan No. 261/2019) from the Ministry of Agriculture, Indonesia. Sludge from the paper industry has the potency to be soil amendment because it meets the requirement from Kepmentan No. 261/2019. Its pH was neutral (6.9), the macro and micronutrients contents fit the requirement, and it had no microbial contaminant content. However, the organic C was under expectation, and it has over Hg content.

Effect of reservoir pressure and total organic content on adsorbed gas production in shale reservoirs: a numerical modelling study

Adsorbed gas plays a key role in organic-rich shale gas production due to its potential to contribute up to 60% of the total gas production. The amount of gas potentially adsorbed on organic-rich shale is controlled by thermal maturity, total organic content (TOC), and reservoir pressure. Whilst those factors have been extensively studied in literature, the factors governing desorption behaviour have not been elucidated, presenting a substantial impediment in managing and predicting the performance of shale gas reservoirs. Therefore, in this paper, a simulation study was carried out to examine the effect of reservoir depth and TOC on the contribution of adsorbed gas to shale gas production. The multi-porosity and multi-permeability model, hydraulic fractures, and local grid refinements were incorporated in the numerical modelling to simulate gas storage and transient behaviour within matrix and fracture regions. The model was then calibrated using core data analysis from literature for Barnett shales. Sensitivity analysis was performed on a range of reservoir depth and TOC to quantify and investigate the contribution of adsorbed gas to total gas production. The simulation results show the contribution of adsorbed gas to shale gas production decreases with increasing reservoir depth regardless of TOC. In contrast, the contribution increases with increasing TOC. However, the impact of TOC on the contribution of adsorbed gas production becomes minor with increasing reservoir depth (pressure). Moreover, the results suggest that adsorbed gas may contribute up to 26% of the total gas production in shallow (below 4,000 feet) shale plays. These study findings highlight the importance of Langmuir isothermal behaviour in shallow shale plays and enhance understanding of desorption behaviour in shale reservoirs; they offer significant contributions to reaching the target of net-zero CO2 emissions for energy transitions by exhibiting insights in the application of enhanced shale gas recovery and CO2 sequestration — in particular, the simulation results suggest that CO2 injection into shallow shale reservoirs rich in TOC, would give a much better performance to unlock the adsorbed gas and sequestrate CO2 compared to deep shales.

Sediment oxygen demand in streams : lab measurements underestimate in situ rates substantially

Global warming is expected to affect stream metabolism significantly; and higher temperatures may lead to higher respiration and thus higher risk of oxygen depletion. It is, therefore, crucial to obtain reliable data on the oxygen dynamics in the different stream compartments. Determination of sediment oxygen demand (SOD) is typically based on lab or field measurement using cores or benthic chamber in which the actual physical conditions in the streams are not possible to mimic perfectly. We compared SOD based on lab core incubations with SOD measured in situ in stream sections where the oxygen exchange between water and air was eliminated artificially. The in situ SOD increased with increasing oxygen concentrations and both the temperature and the oxygen dependency of SOD increased with increasing organic content in the surface sediment. The laboratory rates reached 17 - 83% of the rates obtained in situ. The percentages were especially low at low stream velocity, likely reflecting a pure imitation of the physical conditions near the sediment in the lab when the sediment organic content was high (at low velocity). Therefore, alternative methods, simulating the natural horizontal water flow, are needed to provide reliable information on SOD in streams.