Traditionally, the depth of maximum shower development Xmax has been used as a surrogate observable for composition. Here we present the possibility of a new methodology to discriminate between light and heavy cosmic-ray primaries on an event-by-event basis. This method is based on comparisons between detected radio signals and Monte Carlo simulations, but instead of first reconstructing Xmax, we try to infer the cosmic-ray composition directly. We show that a large discrimination efficiency could in principle be reached for zenith angles above θ≃65°, even when some of the typical uncertainties in radio detection are taken into account.