Abstract
Review of the available results appearing in the recent literature is presented focusing particularly upon the effects of metallic ions such as Cr, Cu, Zn, Cd, Hg, V, Zn, Ni and Co. Some original data involving the effects of Na are presented and discussed. Development of parameters used in evaluating the influence of toxic or inhibitory species on the mixed microbial population of an activated sludge system is of crucial importance and different techniques employed such as BOD-COD-TOC-removal rates, Oxygen Uptake Rate, and others are discussed, showing relative inadequacy of currently applied assays.
From the data available, certain trends can be discerned. There is a definite threshold concentration for each metallic ion, depending on the organic load of the feed. In the order of increasing toxicity to activated sludge systems reflected in lower BOD removals the following metals have been listed as inhibiting factors at concentrations starting from 1 ppm applied on a continuous basis: hexavalent chromium, cobalt, zinc, cadmium, trivalent chromium, copper and nickel.
Metals in combination have not been reported to exhibit any significantly different effects as compared to those observed with individually introduced metallic ions. Tolerance of some activated sludge systems to shock loadings by various inorganic ions and metals is reviewed. The conclusions are of particular importance for estimating the performance of biox systems handling industrial effluents which are likely to contain toxic components of inorganic or metallic nature.
Soluble substrate removal determination through intracellular storage in high-rate activated sludge systems using stoichiometric mass balance approach