Catalytic fast pyrolysis of mushroom waste to upgraded bio-oil products via pre-coked modified HZSM-5 catalyst

2016 ◽  
Vol 212 ◽  
pp. 6-10 ◽  
Author(s):  
Jia Wang ◽  
Zhaoping Zhong ◽  
Kuan Ding ◽  
Zeyu Xue
2021 ◽  
Vol 14 ◽  
pp. 1-11
Author(s):  
Haryanti Yahaya ◽  
Rozzeta Dollah ◽  
Norsahika Mohd Basir ◽  
Rohit Karnik ◽  
Halimaton Hamdan

Oil palm empty fruit bunch (EFB) biomass is a potential source of renewable energy. Catalytic fast-pyrolysis batch process was initially performed to convert oil palm EFB into bio-oil, followed by its refinement to jet bio-fuel. Crystalline zeolites A and Y; synthesised from rice husk ash (RHA), were applied as heterogeneous catalysts. The catalytic conversion of oil palm EFB to bio-oil was conducted at a temperature range of 320-400°C with zeolite A catalyst loadings of 0.6 - 3.0 wt%. The zeolite catalysts were characterised by XRD, FTIR and FESEM. The bio-oil and jet bio-fuel products were analysed using GC-MS and FTIR. The batch fast-pyrolysis reaction was optimised at 400°C with a catalyst loading of 1.0 wt%, produced 42.7 wt% yields of liquid bio-oil, 35.4 wt% char and 21.9 wt% gaseous products. Analysis by GCMS indicates the compound distribution of the liquid bio-oil are as follows: hydrocarbons (23%), phenols (61%), carboxylic acids (0.7%), ketones (2.7%), FAME (7.7%) and alcohols (0.8%). Further refinement of the liquid bio-oil by catalytic hydrocracking over zeolite Y produced jet bio-fuel, which contains 63% hydrocarbon compounds (C8-C18) and 16% of phenolic compounds.


2018 ◽  
Vol 37 (2) ◽  
pp. 157-167 ◽  
Author(s):  
Ismail Cem Kantarli ◽  
Stylianos D Stefanidis ◽  
Konstantinos G Kalogiannis ◽  
Angelos A Lappas

The objective of this study was to examine the potential of poultry wastes to be used as feedstock in non-catalytic and catalytic fast pyrolysis processes, which is a continuation of our previous research on their conversion into biofuel via slow pyrolysis and hydrothermal conversion. Both poultry meal and poultry litter were examined, initially in a fixed bed bench-scale reactor using ZSM-5 and MgO as catalysts. Pyrolysis of poultry meal yielded high amounts of bio-oil, while pyrolysis of poultry litter yielded high amounts of solid residue owing to its high ash content. MgO was found to be more effective for the deoxygenation of bio-oil and reduction of undesirable compounds, by converting mainly the acids in the pyrolysis vapours of poultry meal into aliphatic hydrocarbons. ZSM-5 favoured the formation of both aromatic compounds and undesirable nitrogenous compounds. Overall, all bio-oil samples from the pyrolysis of poultry wastes contained relatively high amounts of nitrogen compared with bio-oils from lignocellulosic biomass, ca. 9 wt.% in the case of poultry meal and ca. 5–8 wt.% in the case of poultry litter. This was attributed to the high nitrogen content of the poultry wastes, unlike that of lignocellulosic biomass. Poultry meal yielded the highest amount of bio-oil and was selected as optimum feedstock to be scaled-up in a semi-pilot scale fluidised bed biomass pyrolysis unit with the ZSM-5 catalyst. Pyrolysis in the fluidised bed reactor was more efficient for deoxygenation of the bio-oil vapours, as evidenced from the lower oxygen content of the bio-oil.


2018 ◽  
Vol 5 (11) ◽  
pp. 23456-23465
Author(s):  
Suchithra Thangalazhy-Gopakumar ◽  
Chi Wei Lee ◽  
Suyin Gan ◽  
Hoon Kiat Ng ◽  
Lai Yee Lee

ACS Omega ◽  
2021 ◽  
Author(s):  
Mudassir Hussain Tahir ◽  
Rana Muhammad Irfan ◽  
Muhammad Bilal Hussain ◽  
Hesham Alhumade ◽  
Yusuf Al-Turki ◽  
...  

BioResources ◽  
2014 ◽  
Vol 9 (3) ◽  
Author(s):  
Zhi-Bo Zhang ◽  
Qiang Lu ◽  
Xiao-Ning Ye ◽  
Ling-Ping Xiao ◽  
Chang-Qing Dong ◽  
...  

Author(s):  
Nuttapan Promsampao ◽  
Nuwong Chollacoop ◽  
Adisak Pattiya

Ex-situ catalytic fast pyrolysis (ex-CFP) of biomass applying ZSM-5 catalysts is an effective method for deoxygenating the pyrolysis vapour, thus producing low-oxygen bio-oil in a single step. The catalysts deactivate...


2015 ◽  
Vol 6 (7) ◽  
pp. 1069 ◽  
Author(s):  
Widodo Wahyu Purwanto ◽  
Dijan Supramono ◽  
Rahma Muthia ◽  
Muhamad Fakri Firdaus

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