The cement-based composite shielding materials filled with carbon materials such as ordinary carbon materials (graphite, coke and carbon black), carbon fiber and nano-carbon materials (carbon nano-tube and nano-carbon black) were prepared. The relationship of conductivity and shielding effectiveness in a frequency range of 100 KHz~1.5 GHz was studied. The electric properties of cement-based composites filled with carbon fiber is better than other carbon materials. With the contents of carbon fiber of 5.vol%, the average shielding effectiveness is about 37 dB and the maximum shielding effectiveness reaches 40 dB.