Emergence of Dynamical Disorder and Phase Metastability in Carbon Nanobowls

Carbon ◽  
2021 ◽  
Author(s):  
Mattia Gaboardi ◽  
Ian Silverwood ◽  
Balthasar Braunewell ◽  
Jay Siegel ◽  
Felix Fernandez-Alonso
Keyword(s):  
Dynamical Disorder

scholarly journals Phase Polymorphism of [Co(DMSO)6](BF4)2 Studied by Differential Scanning Calorimetry

2006 ◽  
Vol 61 (3-4) ◽  
pp. 180-188 ◽  
Author(s):  
Anna Migdał-Mikuli ◽  
Łukasz Skoczylas ◽  
Elżbieta Szostak
Keyword(s):  
Differential Scanning Calorimetry ◽  
Phase Transitions ◽  
Melting Point ◽  
Title Compound ◽  
Metastable Phases ◽  
Scanning Calorimetry ◽  
Phase Polymorphism ◽  
Solid Phases ◽  
High Degree ◽  
Dynamical Disorder

Five solid phases of [Co(DMSO)6](BF4)2 have been detected by differential scanning calorimetry (DSC). Phase transitions were detected between the following solid phases: stable KIb↔ stable KIa at T̅C4 = (328±2) K, metastable KIII ↔ undercooled phase K0 at T̅C3 = (383±4) K, metastable KII ↔ undercooled K0 at T̅C2 = (399±2) K and stable KIa ↔ stable K0 at T̅C1 = (404±1) K. The title compound melts at Tm = 440 K. From the entropy changes at the melting point and at phase transitions it can be concluded that the phases K0 and undercooled K0 are orientationally dynamically disordered crystals. The stable phases KIa, KIb are ordered solid phases. The metastable phases KII and KIII are probably solid phases with a high degree of orientational dynamical disorder

Dynamical Disorder in the DNA Hydration Shell

2016 ◽  
Vol 138 (24) ◽  
pp. 7610-7620 ◽  
Author(s):  
Elise Duboué-Dijon ◽  
Aoife C. Fogarty ◽  
James T. Hynes ◽  
Damien Laage
Keyword(s):  
Hydration Shell ◽  
Dna Hydration ◽  
Dynamical Disorder

A MODEL FOR OPTICAL ABSORPTION OF AMORPHOUS GaAs IN THE FAR-INFRARED RANGE BY USING AN OPERATIONAL TECHNIQUE

1999 ◽  
Vol 13 (25) ◽  
pp. 919-923 ◽  
Author(s):  
M. A. GRADO-CAFFARO ◽  
M. GRADO-CAFFARO
Keyword(s):  
Optical Absorption ◽  
Absorption Coefficient ◽  
Far Infrared ◽  
Structural Disorder ◽  
Optical Absorption Coefficient ◽  
Infrared Range ◽  
Phonon Density ◽  
Phonon Density Of States ◽  
Operational Technique ◽  
Dynamical Disorder

By considering a sample of amorphous GaAs with a small zone of dynamical disorder, an expression for the optical absorption coefficient and phonon density of states in the low region of the far-infrared range is obtained. To get to this end, absorption corresponding to structural disorder is neglected.

Dynamical disorder in diffusion-limited reactions

2002 ◽  
Vol 306 ◽  
pp. 169-179 ◽  
Author(s):  
M. Moreau ◽  
G. Oshanin ◽  
O. Bénichou
Keyword(s):  
Diffusion Limited ◽  
Dynamical Disorder

Static and dynamical disorder ofNiCl2clusters intercalated in graphite

1992 ◽  
Vol 45 (16) ◽  
pp. 9357-9361 ◽  
Author(s):  
G. Faraci ◽  
S. La Rosa ◽  
A. R. Pennisi ◽  
S. Mobilio ◽  
I. Pollini
Keyword(s):  
Dynamical Disorder
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