Liquid-phase selective oxidation catalysis with metal-organic frameworks

2016 ◽  
Vol 278 ◽  
pp. 22-29 ◽  
Author(s):  
Oxana A. Kholdeeva
Keyword(s):  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Oxidation Catalysis ◽  
Metal Organic

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

scholarly journals Metal‐Organic Frameworks: Metal−Organic Frameworks for Liquid Phase Applications (Adv. Sci. 5/2021)

2021 ◽  
Vol 8 (5) ◽  
pp. 2170025
Author(s):  
Anjaiah Nalaparaju ◽  
Jianwen Jiang
Keyword(s):  
Liquid Phase ◽  
Metal Organic Frameworks ◽  
Metal Organic

Liquid Phase Oxidation of Organic Compounds by Metal-Organic Frameworks

2013 ◽  
pp. 371-409 ◽  
Author(s):  
Young Kyu Hwang ◽  
GÉrard FÉrey ◽  
U-Hwang Lee ◽  
Jong-San Chang
Keyword(s):  
Liquid Phase ◽  
Organic Compounds ◽  
Metal Organic Frameworks ◽  
Liquid Phase Oxidation ◽  
Oxidation Of Organic Compounds ◽  
Phase Oxidation ◽  
Metal Organic

Toward Liquid Phase Processable Metal Organic Frameworks: Dream or Reality?

2021 ◽  
Author(s):  
Daria Poloneeva ◽  
Shuvo Jit Datta ◽  
Luis Garzon-Tovar ◽  
Sara Durini ◽  
Magnus Rueping ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Metal Organic Frameworks ◽  
Metal Organic

Engineering a homogeneous alloy-oxide interface derived from metal-organic frameworks for selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

2020 ◽  
Vol 270 ◽  
pp. 118805 ◽  
Author(s):  
Yu-Te Liao ◽  
Van Chi Nguyen ◽  
Nozomu Ishiguro ◽  
Allison P. Young ◽  
Chia-Kuang Tsung ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Oxide Interface ◽  
Metal Organic ◽  
Furandicarboxylic Acid

Oriented Circular Dichroism Analysis of Chiral Surface-Anchored Metal-Organic Frameworks Grown by Liquid-Phase Epitaxy and upon Loading with Chiral Guest Compounds

2014 ◽  
Vol 20 (32) ◽  
pp. 9879-9882 ◽  
Author(s):  
Zhi-Gang Gu ◽  
Jochen Bürck ◽  
Angela Bihlmeier ◽  
Jinxuan Liu ◽  
Osama Shekhah ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Liquid Phase ◽  
Liquid Phase Epitaxy ◽  
Metal Organic Frameworks ◽  
Circular Dichroism Analysis ◽  
Metal Organic ◽  
Circular Dichroïsm ◽  
Chiral Surface

Rational modulating electronegativity of substituents in amorphous metal-organic frameworks for water oxidation catalysis

2020 ◽  
Vol 45 (16) ◽  
pp. 9723-9732 ◽  
Author(s):  
Sanjiang Pan ◽  
Xiangbin Kong ◽  
Qixing Zhang ◽  
Qiaojing Xu ◽  
Manjing Wang ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Metal Organic Frameworks ◽  
Amorphous Metal ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis ◽  
Metal Organic

Fabrication of free-standing ultrathin films of porous metal-organic frameworks by liquid-phase epitaxy and subsequent delamination

2010 ◽  
Vol 4 (8-9) ◽  
pp. 197-199 ◽  
Author(s):  
Masih Darbandi ◽  
Hasan K. Arslan ◽  
Osama Shekhah ◽  
Asif Bashir ◽  
Alexander Birkner ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Epitaxy ◽  
Ultrathin Films ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Free Standing ◽  
Metal Organic
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