scholarly journals From mononuclear iron phthalocyanines in catalysis to μ-nitrido diiron complexes and beyond

2021 ◽  
Author(s):  
Alexander B. Sorokin
Keyword(s):  
Mononuclear Iron

An insight to the noncovalent interactions in two triamine based mononuclear iron(III) Schiff base complexes with special emphasis on the formation of Br•••π halogen bonding

CrystEngComm ◽  
2021 ◽  
Author(s):  
Shouvik Chattopadhyay ◽  
Tanmoy Basak ◽  
Antonio Frontera
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Noncovalent Interactions ◽  
Halogen Bonding ◽  
Schiff Base Complexes ◽  
X Ray ◽  
Mononuclear Iron

Two mononuclear iron(III) complexes, [FeL1Cl]∙CH3CN (1) and [FeL2(N3)] (2) {H2L1= N,N′-bis(5-chlorosalicylidene)diethylenetriamine and H2L2= N,N′-bis(5-bromosalicylidene)diethylenetriamine}, have been synthesized and characterized by X-ray crystallographic studies. In the solid state, there are strong...

Mononuclear Iron(III) Complexes as Functional Models of Catechol Oxidases and Catalases

2015 ◽  
Vol 2015 (21) ◽  
pp. 3478-3484 ◽  
Author(s):  
Elena Badetti ◽  
Blerina Gjoka ◽  
Eszter Márta Nagy ◽  
Gérald Bernardinelli ◽  
Peter E. Kündig ◽  
...  
Keyword(s):  
Mononuclear Iron ◽  
Functional Models

Spin-State Ordering on One Sub-lattice of a Mononuclear Iron(III) Spin Crossover Complex Exhibiting LIESST and TIESST

2014 ◽  
Vol 20 (19) ◽  
pp. 5613-5618 ◽  
Author(s):  
Kevin D. Murnaghan ◽  
Chiara Carbonera ◽  
Loic Toupet ◽  
Michael Griffin ◽  
Marinela M. Dîrtu ◽  
...  
Keyword(s):  
Spin State ◽  
Spin Crossover ◽  
Mononuclear Iron

scholarly journals Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

2016 ◽  
Vol 45 (28) ◽  
pp. 11267-11271 ◽  
Author(s):  
F. Pointillart ◽  
X. Liu ◽  
M. Kepenekian ◽  
B. Le Guennic ◽  
S. Golhen ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Near Infrared ◽  
Spin Transition ◽  
Infrared Light ◽  
Near Infrared Light ◽  
Mononuclear Iron

A thermal and photo-induced spin transition in a tetrathiafulvalene-based Fe(ii) complex.

scholarly journals Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding

2015 ◽  
Vol 22 (1) ◽  
pp. 331-339 ◽  
Author(s):  
Sipeng Zheng ◽  
Niels R. M. Reintjens ◽  
Maxime A. Siegler ◽  
Olivier Roubeau ◽  
Elisabeth Bouwman ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
High Temperature ◽  
Spin State ◽  
Spin Crossover ◽  
Mononuclear Iron

scholarly journals Structural movies of the gradual spin-crossover in a molecular complex at various physical scales

2016 ◽  
Vol 18 (40) ◽  
pp. 28307-28315 ◽  
Author(s):  
S. Lakhloufi ◽  
M. H. Lemée-Cailleau ◽  
G. Chastanet ◽  
P. Rosa ◽  
N. Daro ◽  
...  
Keyword(s):  
Spin State ◽  
Molecular Complex ◽  
Spin Crossover ◽  
Structural Determination ◽  
Thermally Induced ◽  
Mononuclear Iron

The thermally induced Spin-CrossOver (SCO) undergone by the mononuclear iron(ii) complex [Fe(PM-AzA)2(NCS)2] (PM = N-2′-pyridylmethylene, AzA = 4-(phenylazo)aniline) is fully pictured by a quasi-continuous structural determination all along the spin-state modification within the sample.

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