Bimetallic Cu-Pt catalysts over nanoshaped ceria for hydrogen production via methanol decomposition

2021 ◽  
Author(s):  
Luis López-Rodríguez ◽  
Daniel G. Araiza ◽  
Diana G. Arcos ◽  
Antonio Gómez-Cortés ◽  
Gabriela Díaz
2004 ◽  
Vol 842 ◽  
Author(s):  
Ya Xu ◽  
Satoshi Kameoka ◽  
Kyosuke Kishida ◽  
Masahiko Demura ◽  
An-pang Tsai ◽  
...  

ABSTRACTThe stability of catalytic activity and selectivity of Ni3Al for methanol decomposition were studied by life test at 633 K on the alkali-leached powder samples. The characterization of the samples was carried out by X-ray diffraction, inductively coupled plasma (ICP) analysis, SEM observation, and surface area measurement. The life test showed that the alkali-leached Ni3Al exhibits a very stable activity and a high selectivity for methanol decomposition. The surface characterization after reaction suggests that the high selectivity and stable activity may be attributed to the formation of tiny particles and porous structure which increased the surface area significantly during reaction. These results indicate a possibility of Ni3Al as a catalyst for hydrogen production reaction.


2012 ◽  
Vol 706-709 ◽  
pp. 1052-1057 ◽  
Author(s):  
Ya Xu ◽  
Masahiko Demura ◽  
Toshiyuki Hirano ◽  
Yasuyuki Kaneno ◽  
Takayuki Takasugi

The objective of this study is to investigate the catalytic properties of intermetallic Ni3Fe foil. We fabricated Ni3Fe foil of 30 µm in thickness by a metallurgical process, and examined the catalytic activity of the Ni3Fe foil for methanol decomposition from 513 to 973 K. The Ni3Fe foil showed activity for methanol decomposition above 623 K. The activity increased with the increase of reaction temperature. Surface analysis revealed that a surface structure of fine Ni-Fe particles dispersed on carbon nanofibers was formed on the foil during the reaction. The activity is attributed to the formation of this fine structure.


2010 ◽  
Vol 46 (35) ◽  
pp. 6494 ◽  
Author(s):  
Qingsheng Gao ◽  
Chenxi Zhang ◽  
Sinong Wang ◽  
Wei Shen ◽  
Yahong Zhang ◽  
...  

2019 ◽  
Vol 149 (10) ◽  
pp. 2671-2682 ◽  
Author(s):  
Yahui Wei ◽  
Shiyan Li ◽  
Jiang Jing ◽  
Meng Yang ◽  
Chengfa Jiang ◽  
...  

Author(s):  
Fufeng Cai ◽  
Yanjiao Guo ◽  
Jessica Juweriah Ibrahim ◽  
Jun Zhang ◽  
Yuhan Sun

2005 ◽  
Vol 475-479 ◽  
pp. 755-758 ◽  
Author(s):  
Ya Xu ◽  
Satoshi Kameoka ◽  
Kyosuke Kishida ◽  
Masahiko Demura ◽  
An Pong Tsai ◽  
...  

Ni3Al has attractive high temperature properties, such as high strength and good oxidation/corrosion resistance, and is possible to be used for high temperature chemical processing and manufacture. Until now, the catalytic properties of Ni3Al were rarely investigated since the leaching of aluminum from Ni3Al is difficult to obtain a porous Raney-Ni compared to NiAl3 and Ni2Al3. In the present work, the catalytic properties of Ni3Al were examined for hydrogen production reactions from methanol. It was found that alkali-leached Ni3Al showed high activity for methanol decomposition (CH3OH→ 2H2+CO). Furthermore, Ni3Al catalysts suppress the formation of methane, i.e. they show higher selectivity for the methanol decomposition reaction than Ni catalyst. These results indicate a possibility for Ni3Al used as a catalyst for hydrogen production reaction.


2016 ◽  
Vol 91 (8) ◽  
pp. 2198-2204 ◽  
Author(s):  
Cinthia García-Mendoza ◽  
Socorro Oros-Ruiz ◽  
Agileo Hernández-Gordillo ◽  
Rosendo López ◽  
Gabriela Jácome-Acatitla ◽  
...  

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