“Series and parallel” design of ether linkage and imidazolium cation synergistically regulated four-armed polymerized ionic liquid for all-solid-state polymer electrolyte

2021 ◽  
Author(s):  
Zehui Xie ◽  
Yang Zhou ◽  
Canhui Ling ◽  
Xinlin Zhu ◽  
Zhao Fang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
Ether Linkage ◽  
Imidazolium Cation ◽  
Polymerized Ionic Liquid ◽  
Parallel Design

scholarly journals Thermostable gel polymer electrolyte based on succinonitrile and ionic liquid for high-performance solid-state supercapacitors

2016 ◽  
Vol 328 ◽  
pp. 510-519 ◽  
Author(s):  
Gaind P. Pandey ◽  
Tao Liu ◽  
Cody Hancock ◽  
Yonghui Li ◽  
Xiuzhi Susan Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
High Performance ◽  
Gel Polymer Electrolyte

Anion−π and Halide–Halide Nonbonding Interactions in a New Ionic Liquid Based on Imidazolium Cation with Three-Dimensional Magnetic Ordering in the Solid State

2014 ◽  
Vol 53 (16) ◽  
pp. 8384-8396 ◽  
Author(s):  
Abel García-Saiz ◽  
Imanol de Pedro ◽  
Pedro Migowski ◽  
Oriol Vallcorba ◽  
Javier Junquera ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Three Dimensional ◽  
Magnetic Ordering ◽  
Imidazolium Cation

Pulse Polymerized Poly(3,4-ethylenedioxythiophene) Electrodes For Solid-State Supercapacitors with Ionic Liquid Gel Polymer Electrolyte

2012 ◽  
Vol 1448 ◽  
Author(s):  
G. P. Pandey ◽  
A. C. Rastogi
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
Photoelectron Spectroscopy ◽  
Gel Polymer Electrolyte ◽  
Charge Transfer Resistance ◽  
Polymer Chains ◽  
Transfer Resistance ◽  
Spectroscopy Studies ◽  
Highly Porous

ABSTRACTPoly(3,4-ethylenedioxythiophene) (PEDOT) electrodes are prepared by a novel ultrashort galvanic pulse electropolymerization technique for application in solid-state supercapacitors. Microstructure studies using scanning electron microscopy (SEM) show that PEDOT electrodes deposited by pulse polymerization are highly porous as compared to the conventional potentiostatic polymerization. In addition, as revealed by the X-ray photoelectron spectroscopy (XPS) studies in the PEDOT films formed by pulse polymerization, the polymer chains are fully conjugated with the dopant ClO4- ions. Solid-state supercapacitor cells using pulse polymerized PEDOT electrodes and ionic liquid gel polymer electrolyte were fabricated and characterized. The impedance spectroscopy studies show that the pulse polymerized PEDOT electrode have specific capacitance value of ∼ 65 F g-1 as compared to ∼52 F g-1for potentiostatically polymerized PEDOT and significantly lower interfacial and charge transfer resistance. Cyclic voltammetry (CV) and galvanostatic charge-discharge characterization show highly capacitive behavior of the supercapacitor cells in the solid-state configuration.

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