Solid-State Supercapacitors Based on Pulse Polymerized Poly(3,4-ethylenedioxythiophene) Electrodes and Ionic Liquid Gel Polymer Electrolyte

2012 ◽  
Vol 159 (10) ◽  
pp. A1664-A1671 ◽  
Author(s):  
G. P. Pandey ◽  
A. C. Rastogi
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte

scholarly journals Thermostable gel polymer electrolyte based on succinonitrile and ionic liquid for high-performance solid-state supercapacitors

2016 ◽  
Vol 328 ◽  
pp. 510-519 ◽  
Author(s):  
Gaind P. Pandey ◽  
Tao Liu ◽  
Cody Hancock ◽  
Yonghui Li ◽  
Xiuzhi Susan Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
High Performance ◽  
Gel Polymer Electrolyte

Pulse Polymerized Poly(3,4-ethylenedioxythiophene) Electrodes For Solid-State Supercapacitors with Ionic Liquid Gel Polymer Electrolyte

2012 ◽  
Vol 1448 ◽  
Author(s):  
G. P. Pandey ◽  
A. C. Rastogi
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
Photoelectron Spectroscopy ◽  
Gel Polymer Electrolyte ◽  
Charge Transfer Resistance ◽  
Polymer Chains ◽  
Transfer Resistance ◽  
Spectroscopy Studies ◽  
Highly Porous

ABSTRACTPoly(3,4-ethylenedioxythiophene) (PEDOT) electrodes are prepared by a novel ultrashort galvanic pulse electropolymerization technique for application in solid-state supercapacitors. Microstructure studies using scanning electron microscopy (SEM) show that PEDOT electrodes deposited by pulse polymerization are highly porous as compared to the conventional potentiostatic polymerization. In addition, as revealed by the X-ray photoelectron spectroscopy (XPS) studies in the PEDOT films formed by pulse polymerization, the polymer chains are fully conjugated with the dopant ClO4- ions. Solid-state supercapacitor cells using pulse polymerized PEDOT electrodes and ionic liquid gel polymer electrolyte were fabricated and characterized. The impedance spectroscopy studies show that the pulse polymerized PEDOT electrode have specific capacitance value of ∼ 65 F g-1 as compared to ∼52 F g-1for potentiostatically polymerized PEDOT and significantly lower interfacial and charge transfer resistance. Cyclic voltammetry (CV) and galvanostatic charge-discharge characterization show highly capacitive behavior of the supercapacitor cells in the solid-state configuration.

High energy density and high working voltage of a quasi-solid-state supercapacitor with a redox-active ionic liquid added gel polymer electrolyte

2019 ◽  
Vol 43 (47) ◽  
pp. 18935-18942 ◽  
Author(s):  
Cheng-Long Geng ◽  
Le-Qing Fan ◽  
Chun-Yan Wang ◽  
Yong-Lan Wang ◽  
Si-Jia Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Energy Density ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte ◽  
High Energy ◽  
High Energy Density ◽  
Redox Active

A redox-active gel polymer electrolyte with a high working voltage was synthesized and used for assembling a quasi-solid-state supercapacitor possessing high energy density.

High energy density and low self-discharge of a quasi-solid-state supercapacitor with carbon nanotubes incorporated redox-active ionic liquid-based gel polymer electrolyte

2020 ◽  
Vol 331 ◽  
pp. 135425 ◽  
Author(s):  
Le-Qing Fan ◽  
Qiu-Mei Tu ◽  
Cheng-Long Geng ◽  
Jian-Ling Huang ◽  
Yun Gu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Ionic Liquid ◽  
Solid State ◽  
Energy Density ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte ◽  
High Energy ◽  
High Energy Density ◽  
Redox Active

High-Performance Ionic Liquid-Based Gel Polymer Electrolyte Incorporating Anion-Trapping Boron Sites for All-Solid-State Supercapacitor Application

2018 ◽  
Vol 10 (46) ◽  
pp. 39570-39580 ◽  
Author(s):  
Mengyuan Jin ◽  
Yifan Zhang ◽  
Chaojing Yan ◽  
Yanbao Fu ◽  
Yanhui Guo ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Polymer Electrolyte ◽  
High Performance ◽  
Gel Polymer Electrolyte ◽  
Supercapacitor Application

scholarly journals Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 297 ◽  
Author(s):  
Haiyan Du ◽  
Zemin Wu ◽  
Yuyu Xu ◽  
Shaoze Liu ◽  
Huimin Yang
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Electrochemical Performance ◽  
Polymer Electrolyte ◽  
Electrochemical Impedance ◽  
Elastic Recovery ◽  
Gel Polymer Electrolyte ◽  
Carbon Paper ◽  
Self Healing ◽  
Potential Applications

In this work, solid-state polymer supercapacitor (SSC) was assembled using poly(3,4-ethylenedioxythiophene/carbon paper (PEDOT/CP) as an electrode and ionic liquid (1-butyl-3-methylimidazole tetrafluoroborate)/polyvinyl alcohol/sulfuric acid (IL/PVA/H2SO4) as a gel polymer electrolyte (GPE). The GPE was treated through freezing–thawing (F/T) cycles to improve the electrochemical properties of PEDOT SSC. Cyclic voltammetry (CV), galvanostatic charge–discharge measurements (GCD) and electrochemical impedance spectroscopy (EIS) techniques and conductivity were carried out to study the electrochemical performance. The results showed that the SSC based on ionic liquid GPE (SSC-IL/PVA/H2SO4) has a higher specific capacitance (with the value of 86.81 F/g at 1 mA/cm2) than the SSC-PVA/H2SO4.The number of F/T cycles has a great effect on the electrochemical performance of the device. The energy density of the SSC treated with 3 F/T cycles was significantly improved, reaching 176.90 Wh/kg. Compared with the traditional electrolytes, IL GPE has the advantages of high ionic conductivity, less volatility, non-flammability and wider potential window. Moreover, the IL GPE has excellent elastic recovery and self-healing performance, leading to its great potential applications in flexible or smart energy storage equipment.

Sign in / Sign up

Export Citation Format

Share Document