A polymer nanocomposite coating with enhanced hydrophilicity, antibacterial and antibiofouling properties: Role of polymerizable emulsifier/anionic ligand

2020 ◽  
Vol 379 ◽  
pp. 122268 ◽  
Author(s):  
Yu Chen ◽  
Yong Ding ◽  
Junping Zheng
Coatings ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 280 ◽  
Author(s):  
Abdul Mohammed

Due to a growing demand for protecting metallic components from wear and tear, polymer coatings are being extensively researched and developed as one of the most effective and efficient solutions to reduce friction and wear in demanding tribological applications. The present study focuses on developing a polymer nanocomposite coating of ultra-high molecular polyethylene (UHMWPE) reinforced with different loadings (0.5, 3, 5, and 10 wt %) of alumina to protect steel surfaces. Wear tests were conducted on the coated samples using a tribometer with a ball-on-disk configuration, sliding against a 440C hardened stainless steel ball as a counterface to evaluate the wear life and the load-bearing capacity of the developed coatings. Micro-indentation, energy dispersive X-ray spectroscopy, scanning electron microscopy, and optical profilometry techniques were used to characterize the coatings in terms of hardness, dispersion of the nanofillers, morphology, and wear mechanisms, respectively. Results showed that the UHMWPE nanocomposite coating reinforced with 3 wt % and 5 wt % of alumina did not fail, even until 250,000 cycles at a normal load of 12 N and a linear speed of 0.1 m/s, showing a significant improvement in wear resistance as compared to the pristine UHMWPE coating.


2015 ◽  
Vol 48 (22) ◽  
pp. 8369-8375 ◽  
Author(s):  
Brad Miller ◽  
Adam E. Imel ◽  
Wade Holley ◽  
Durairaj Baskaran ◽  
J. W. Mays ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2960
Author(s):  
Sunhyung Kim ◽  
Sol Mi Oh ◽  
So Youn Kim ◽  
Jun Dong Park

Polymers adsorbed on nanoparticles (NPs) are important elements that determine the dispersion of NPs in polymer nanocomposite (PNC) films. While previous studies have shown that increasing the number of adsorbed polymers on NPs can improve their dispersion during the drying process, the exact mechanism remained unclear. In this study, we investigated the role of adsorbed polymers in determining the microstructure and dispersion of NPs during the drying process. Investigation of the structural development of NPs using the synchrotron vertical-small-angle X-ray scattering technique revealed that increasing polymer adsorption suppresses bonding between the NPs at later stages of drying, when they approach each other and come in contact. On the particle length scale, NPs with large amounts of adsorbed polymers form loose clusters, whereas those with smaller amounts of adsorbed polymers form dense clusters. On the cluster length scale, loose clusters of NPs with large amounts of adsorbed polymers build densely packed aggregates, while dense clusters of NPs with small amounts of adsorbed polymers become organized into loose aggregates. The potential for the quantitative control of NP dispersion in PNC films via modification of polymer adsorption was established in this study.


Cellulose ◽  
2019 ◽  
Vol 26 (16) ◽  
pp. 8877-8894 ◽  
Author(s):  
Muhammad Irfan ◽  
Oleksandr Polonskyi ◽  
Alexander Hinz ◽  
Chiara Mollea ◽  
Francesca Bosco ◽  
...  

2005 ◽  
Vol 12 (4) ◽  
pp. 629-643 ◽  
Author(s):  
M. Roy ◽  
J.K. Nelson ◽  
R.K. MacCrone ◽  
L.S. Schadler ◽  
C.W. Reed ◽  
...  

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