Hydrate-based gas separation for working fluid mixtures: application to composition-adjustable organic Rankine cycle

2022 ◽  
pp. 134626
Author(s):  
Yue Zhang ◽  
Ruikai Zhao ◽  
Xianhua Nie ◽  
Shuai Deng ◽  
Weicong Xu ◽  
...  
2020 ◽  
Vol 10 (21) ◽  
pp. 7925
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadehsardari ◽  
Michela Longo

Globally there are several viable sources of renewable, low-temperature heat (below 130 °C), particularly solar energy, geothermal energy, and energy generated from industrial wastes. Increased exploitation of these low-temperature options has the definite potential of reducing fossil fuel consumption with its attendant very harmful greenhouse gas emissions. Researchers have universally identified the organic Rankine cycle (ORC) as a practicable and suitable system to generate electrical power from renewable sources based on its beneficial usage of volatile organic fluids as working fluids (WFs). In recent times, researchers have also shown a preference towards deployment of zeotropic mixtures as ORC WFs because of their capacity to improve thermodynamic performance of ORC systems, a feat enabled through the greater matching of the temperature profiles of the WF and the heat source/sink. This paper demonstrates the thermodynamic, economic and sustainability feasibility, and the notable advantages of using zeotropic mixtures as WFs through a simulation study of an ORC system. The study examines first the thermodynamic performance of ORC systems using zeotropic mixtures to generate electricity powered by a low-temperature solar heat source for building applications. A thermodynamic model is developed with a solar-driven ORC system both with and excluding a regenerator. Twelve zeotropic mixtures with varying compositions are evaluated and compared to identify the best combinations of mixtures that can yield high performance and high efficiency in their system cycles. The study also examines the effects of the volume flow ratio, and evaporation and condensation temperature glides on the ORC’s thermodynamic performance. Following a detailed analysis of each mixture, R245fa/propane and butane/propane are selected for parametric study to investigate the influence of operating parameters on the system’s efficiency and sustainability index. For zeotropic mixtures, results disclosed that there is an optimal composition range within which binary mixtures are inclined to perform more efficiently than the component pure fluids. In addition, a substantial enhancement in cycle efficiency can be obtained by a regenerative ORC, with cycle efficiency ranging between 3.1–9.8% and 8.6–17.4% for ORC both without and with regeneration, respectively. Results also revealed that exploiting zeotropic mixtures could enlarge the limitation experienced in selecting WFs for low-temperature solar ORCs. Moreover, a detailed economic with a sensitivity analysis of the solar ORC system was performed to evaluate the cost of the electricity and other economic criteria. The outcome of this investigation should be useful in the thermo-economic feasibility assessments of solar-driven ORC systems using working fluid mixtures to find the optimum operating range for maximum performance and minimum cost.


2020 ◽  
Vol 92 (1) ◽  
pp. 10906
Author(s):  
Jeroen Schoenmaker ◽  
Pâmella Gonçalves Martins ◽  
Guilherme Corsi Miranda da Silva ◽  
Julio Carlos Teixeira

Organic Rankine Cycle (ORC) systems are increasingly gaining relevance in the renewable and sustainable energy scenario. Recently our research group published a manuscript identifying a new type of thermodynamic cycle entitled Buoyancy Organic Rankine Cycle (BORC) [J. Schoenmaker, J.F.Q. Rey, K.R. Pirota, Renew. Energy 36, 999 (2011)]. In this work we present two main contributions. First, we propose a refined thermodynamic model for BORC systems accounting for the specific heat of the working fluid. Considering the refined model, the efficiencies for Pentane and Dichloromethane at temperatures up to 100 °C were estimated to be 17.2%. Second, we show a proof of concept BORC system using a 3 m tall, 0.062 m diameter polycarbonate tube as a column-fluid reservoir. We used water as a column fluid. The thermal stability and uniformity throughout the tube has been carefully simulated and verified experimentally. After the thermal parameters of the water column have been fully characterized, we developed a test body to allow an adequate assessment of the BORC-system's efficiency. We obtained 0.84% efficiency for 43.8 °C working temperature. This corresponds to 35% of the Carnot efficiency calculated for the same temperature difference. Limitations of the model and the apparatus are put into perspective, pointing directions for further developments of BORC systems.


2021 ◽  
Vol 11 (5) ◽  
pp. 1984
Author(s):  
Ramin Moradi ◽  
Emanuele Habib ◽  
Enrico Bocci ◽  
Luca Cioccolanti

Organic Rankine cycle (ORC) systems are some of the most suitable technologies to produce electricity from low-temperature waste heat. In this study, a non-regenerative, micro-scale ORC system was tested in off-design conditions using R134a as the working fluid. The experimental data were then used to tune the semi-empirical models of the main components of the system. Eventually, the models were used in a component-oriented system solver to map the system electric performance at varying operating conditions. The analysis highlighted the non-negligible impact of the plunger pump on the system performance Indeed, the experimental results showed that the low pump efficiency in the investigated operating range can lead to negative net electric power in some working conditions. For most data points, the expander and the pump isentropic efficiencies are found in the approximate ranges of 35% to 55% and 17% to 34%, respectively. Furthermore, the maximum net electric power was about 200 W with a net electric efficiency of about 1.2%, thus also stressing the importance of a proper selection of the pump for waste heat recovery applications.


2021 ◽  
pp. 1-21
Author(s):  
G.E. Pateropoulos ◽  
T.G. Efstathiadis ◽  
A.I. Kalfas

ABSTRACT The potential to recover waste heat from the exhaust gases of a turboprop engine and produce useful work through an Organic Rankine Cycle (ORC) is investigated. A thermodynamic analysis of the engine’s Brayton cycle is derived to determine the heat source available for exploitation. The aim is to use the aircraft engine fuel as the working fluid of the organic Rankine cycle in order to reduce the extra weight of the waste heat recovery system and keep the thrust-to-weight ratio as high as possible. A surrogate fuel with thermophysical properties similar to aviation gas turbine fuel is used for the ORC simulation. The evaporator design as well as the weight minimisation and safety of the suggested application are the most crucial aspects determining the feasibility of the proposed concept. The results show that there is potential in the exhaust gases to produce up to 50kW of power, corresponding to a 10.1% improvement of the overall thermal efficiency of the engine.


Author(s):  
W Gu ◽  
Y Weng ◽  
Y Wang ◽  
B Zheng

This article describes and evaluates an organic Rankine cycle (ORC) for a waste heat recovery system by both theoretical and experimental studies. Theoretical analysis of several working fluids shows that cycle efficiency is very sensitive to evaporating pressure, but insensitive to expander inlet temperature. Second law analysis was carried out using R600a as a working fluid and a flow of hot air as a heat source, which is not isothermal, along the evaporator. The result discloses that the evaporator's internal and external entropy generation is the main source of total entropy generation. The effect of the heat source temperature, evaporating pressure, and evaporator size on the entropy generation rate is also presented. The obtained useful power is directly linked to the total entropy generation rate according to the Gouy—Stodola theorem. The ORC testing system was established and operated using R600a as a working fluid and hot water as a heat source. The maximum cycle efficiency of the testing system is 5.2 per cent, and the testing result also proves that cycle efficiency is insensitive to heat source temperature, but sensitive to evaporating pressure. The entropy result also shows that internal and external entropy of the evaporator is the main source of total entropy generation.


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