Mn–Nb co-doping in barium titanate ceramics by different solid-state reaction routes for temperature stable and DC-bias free dielectrics

Author(s):  
Piyush Sapkota ◽  
Ichiro Fujii ◽  
Sangwook Kim ◽  
Shintaro Ueno ◽  
Chikako Moriyoshi ◽  
...  
2011 ◽  
Vol 412 ◽  
pp. 275-279 ◽  
Author(s):  
Wei Cai ◽  
Chun Lin Fu ◽  
Ze Bin Lin ◽  
Xiao Ling Deng ◽  
Wei Hai Jiang

La-doped barium titanate ceramics with 0~1.0 at.% La2O3 were prepared by conventional solid state reaction method. The crystal structure and dielectric properties of La-doped barium titanate ceramics were investigated. Lanthanum ions have entered the unit cell and substituted for Ba2+ ions on the A sites of perovskite structure. The a-axis lattice constant increases and the c-axis lattice constant decreases as lanthanum content increases. Addition of lanthanum leads to the fall of the Curie temperature of La-doped BTO ceramics. There are two different doping mechanisms for La-doped BTO ceramics. The dielectric loss of BTO ceramics with 0.3 at.% La2O3 is higher than that of pure BTO ceramics. When lanthanum content is above 0.5 at.%, the dielectric loss of La-doped BTO ceramics decrease with the increasing of lanthanum content. The result of dielectric constant as a function of temperature at different frequencies indicates that La-doped BTO ceramics are not relaxor ferroelectrics but ferroelectrics with diffuse phase transition.


RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2616-2623
Author(s):  
Weijie Zheng ◽  
Jiaqi Lin ◽  
Xinmei Liu ◽  
Wenlong Yang ◽  
Yuanshuo Li

(Ba0.85Ca0.15)(Zr0.1Ti0.9−xCex)O3+ySb ceramics prepared by the conventional solid-state reaction.


Author(s):  
Xiuping Gao ◽  
Tao Liu ◽  
Xiaohui Jiang ◽  
Kai Huang ◽  
Runlin Liu ◽  
...  

A novel near-infrared persistent luminescent phosphor Na2CaSn2Ge3O12 (NCSGO) doped with Ho3+, Er3+, Tm3+ and Yb3+ was synthesized by high-temperature solid-state reaction. The afterglow emission bands located at 1553nm, 801nm and...


2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Vishal Singh ◽  
Shivani Suri ◽  
K. K. Bamzai

The praseodymium modified lead titanate ceramics with composition Pb1-xPrxTi0.96Fe0.02Mo0.02O3 where x = 0.04, 0.06, 0.08, and 0.10 prepared by solid-state reaction technique were subjected to indentation induced hardness testing method. The indentations were induced in the applied load ranging from 0.245 N to 4.90 N. The microhardness varies nonlinearly with load and was best explained by the concept of Newtonian resistance pressure as proposed by Hays and Kendall’s law. Crack propagation, fracture toughness (Kc), brittleness index (Bi), and yield strength (σy) were studied to understand the effect of Pr content on various mechanical parameters. The load independent values were found to increase with the increase in praseodymium content.


2015 ◽  
Vol 655 ◽  
pp. 212-215
Author(s):  
Xin Qiao Zhao ◽  
Yu Jun Zhang ◽  
Xiao Yu Zhang

Novel environment-friendly near-infrared reflective Y5.2Nd0.8MoO12+σ pigments were fabricated by sol-gel and solid-state reaction routes, and the properties of both pigments were compared. The pigments were characterized by XRD, SEM, CIE-L*a*b* color-measurements, and UV-vis-NIR spectroscopy. The results show that pigments obtained by sol-gel routes crystallize completely at 900 °C, much lower than 1300 °C of solid-state reaction routes. Nano-size pigments fabricated by sol-gel routes possess an average grain size of ~ 50 nm, largely finer than 3 μm of solid-state reaction ones. Moreover, the sol-gel processed pigments show a higher near-infrared reflectance than solid-state reaction ones, which are 98.3 % and 91.7 %, respectively, but with a slightly light yellow color hue.


CrystEngComm ◽  
2019 ◽  
Vol 21 (18) ◽  
pp. 2854-2862 ◽  
Author(s):  
Christian Pithan ◽  
Hayato Katsu ◽  
Rainer Waser

The possibility of preparing translucent ferroelectric heavily donor-doped BaTiO3 ceramics rich in TiO2 has been demonstrated by conventional ceramic processing based on the synthesis via the solid state route and on subsequent sintering and annealing at high levels of oxygen partial pressure.


2010 ◽  
Vol 64 (2) ◽  
pp. 170-172 ◽  
Author(s):  
Won-Sik Jung ◽  
Jong-Hyun Kim ◽  
Hyun-Tae Kim ◽  
Dang-Hyok Yoon

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