Sodium dodecyl sulfate coated poly (vinyl) chloride: An alternative support for solid phase extraction of some transition and heavy metals

Chemosphere ◽  
2009 ◽  
Vol 74 (4) ◽  
pp. 583-589 ◽  
Author(s):  
Farzaneh Marahel ◽  
Mehrorang Ghaedi ◽  
Ardeshir Shokrollahi ◽  
Morteza Montazerozohori ◽  
Shahnaz Davoodi
2017 ◽  
Vol 75 (6) ◽  
pp. 1440-1446
Author(s):  
Shahriar Abbasi ◽  
Mehdi ShanbehDehbalai ◽  
Hossein Khani

A new, simple and rapid method for solid phase extraction and preconcentration of trace amounts of cadmium ions using 2-mercaptobenzothiazole/sodium dodecyl sulfate immobilized on magnetite nanoparticles (MBT-SDS-MNPs) was proposed. The method is based on the extraction of cadmium ions via complexation with MBT immobilized on SDS-coated MNPs and their determination by flame atomic absorption spectrometry. The effects of different parameters – pH; eluent type, concentration and volume; amounts of salt and adsorbent; contact time and interfering ions – on the adsorption of cadmium ions were studied. Under optimized conditions, the calibration curve was linear in the range of 10–5,000 μg L−1. Detection limit and relative standard deviation of the proposed method were 0.009 μg L−1 and 2.2%, respectively. The adsorption data were analyzed by Langmuir and Freundlich isotherm models and a maximum adsorption amount of 24.80 mg g−1, a Langmuir adsorption equilibrium constant (b) of 4.62 and Freundlich constants Kf and n of 6.075 mg1–1/n L1/n g−1 and 2.391, respectively, were obtained. Finally, this adsorbent was successfully used for extraction of cadmium from water and food samples.


Química Nova ◽  
2013 ◽  
Vol 36 (9) ◽  
pp. 1354-1359 ◽  
Author(s):  
Ardeshir Shokrollahi ◽  
Morteza Montazerozohori ◽  
Tahere Mehrpour ◽  
Hossein Tavallali ◽  
Batool Zare Khafri ◽  
...  

2019 ◽  
Vol 3 (3) ◽  
pp. 67 ◽  
Author(s):  
Mai Furukawa ◽  
Ikki Tateishi ◽  
Hideyuki Katsumata ◽  
Satoshi Kaneco

In the present study, activated carbon (AC) surface modified with sodium dodecyl sulfate (SDS), written as SDS/AC, was applied as an adsorbent for preconcentration and determination of trace amount of cadmium ions in environmental sample waters. The SDS modification on AC was performed at the same time, while cadmium ions were concentrated in the flow system as solid-phase extraction. After the separation and preconcentration steps, cadmium retained on SDS/AC was eluted with HNO3 and was subsequently determined by flame atomic absorption spectrometry (FAAS). The analytical parameters that influence the quantitative determination of trace cadmium, such as SDS concentration, pH and volume of sample solution, eluent conditions, and interference, were optimized. At the optimum conditions, the general matrix elements had little interference on the proposed procedure. The detection limits was 17 ng·L−1, and the relative standard deviation (RSD) for 12 experiments at 10 µg·L−1 cadmium solutions was 2.8%. The developed method was applied into the analysis of environmental samples spiked cadmium.


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