Two-stage modeling strategy for industrial fluidized bed reactors in gas-phase ethylene polymerization processes

2018 ◽  
Vol 140 ◽  
pp. 68-81 ◽  
Author(s):  
Thirasit Kusolsongtawee ◽  
Pornchai Bumroongsri
Author(s):  
Chih-Hsiang Yang ◽  
Jaclyn P Maher ◽  
Aditya Ponnada ◽  
Eldin Dzubur ◽  
Rachel Nordgren ◽  
...  

Abstract People differ from each other to the extent to which momentary factors, such as context, mood, and cognitions, influence momentary health behaviors. However, statistical models to date are limited in their ability to test whether the association between two momentary variables (i.e., subject-level slopes) predicts a subject-level outcome. This study demonstrates a novel two-stage statistical modeling strategy that is capable of testing whether subject-level slopes between two momentary variables predict subject-level outcomes. An empirical case study application is presented to examine whether there are differences in momentary moderate-to-vigorous physical activity (MVPA) levels between the outdoor and indoor context in adults and whether these momentary differences predict mean daily MVPA levels 6 months later. One hundred and eight adults from a multiwave longitudinal study provided 4 days of ecological momentary assessment (during baseline) and accelerometry data (both at baseline and 6 month follow-up). Multilevel data were analyzed using an open-source program (MixWILD) to test whether momentary strength between outdoor context and MVPA during baseline was associated with average daily MVPA levels measured 6 months later. During baseline, momentary MVPA levels were higher in outdoor contexts as compared to indoor contexts (b = 0.07, p < .001). Participants who had more momentary MVPA when outdoors (vs. indoors) during baseline (i.e., a greater subject-level slope) had higher daily MVPA at the 6 month follow-up (b = 0.09, p < .05). This empirical example shows that the subject-level momentary association between specific context (i.e., outdoors) and health behavior (i.e., physical activity) may contribute to overall engagement in that behavior in the future. The demonstrated two-stage modeling approach has extensive applications in behavioral medicine to analyze intensive longitudinal data collected from wearable sensors and mobile devices.


2011 ◽  
Vol 66 (6) ◽  
pp. 1189-1199 ◽  
Author(s):  
Ahmad Shamiri ◽  
Mohamed Azlan Hussain ◽  
Farouq Sabri Mjalli ◽  
Navid Mostoufi ◽  
Mohammad Saleh Shafeeyan

Author(s):  
Ram G. Rokkam ◽  
Rodney O. Fox ◽  
Michael E. Muhle

Gas-solid flows have numerous industrial applications and are also found in natural processes. They are involved in industries like petrochemical, polymer, pharmaceutical, food and coal. Fluidization is a commonly used gas-solid operation and is widely used in production of polyethylene. Polyethylene is one of the most widely used thermoplastics. Over 60 million tons are produced worldwide every year by both gas-phase and liquid-phase processes. Gas-phase processes are more advantageous and use fluidized-bed reactors (e.g., UNIPOLTM PE PROCESS and Innovene process) for the polymerization reactions. In this work a chemical-reaction-engineering model incorporating a given catalyst size distribution and polymerization kinetics along with the quadrature method of moments is used to predict the final polymer size distribution and temperature. An Eulerian-Eulerian multi-fluid model based on the kinetic theory of granular flow is used to solve the fluidized-bed dynamics and predict behavior such as particle segregation, slug flow and other non-ideal phenomena.


2013 ◽  
Vol 19 (1) ◽  
pp. 13-24 ◽  
Author(s):  
Ahmad Shamiria ◽  
M.A. Hussaina ◽  
Farouq Mjallic ◽  
Navid Mostoufid

A comparative study describing gas-phase propylene polymerization in fluidized-bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.


2015 ◽  
Vol 264 ◽  
pp. 706-719 ◽  
Author(s):  
Ahmad Shamiri ◽  
Suk Wei Wong ◽  
Mohd Fauzi Zanil ◽  
Mohamed Azlan Hussain ◽  
Navid Mostoufi

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