Electrodeposited ternary iron-cobalt-nickel catalyst on nickel foam for efficient water electrolysis at high current density

Author(s):  
Yuangang Li ◽  
Shuli Yang ◽  
Huajing Li ◽  
Gang Li ◽  
Min Li ◽  
...  
2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Guangfu Qian ◽  
Jinli Chen ◽  
Tianqi Yu ◽  
Lin Luo ◽  
Shibin Yin

AbstractDeveloping highly effective and stable non-noble metal-based bifunctional catalyst working at high current density is an urgent issue for water electrolysis (WE). Herein, we prepare the N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet grown on 3D nickel foam (NiCo@C-NiCoMoO/NF) for water splitting. NiCo@C-NiCoMoO/NF exhibits outstanding activity with low overpotentials for hydrogen and oxygen evolution reaction (HER: 39/266 mV; OER: 260/390 mV) at ± 10 and ± 1000 mA cm−2. More importantly, in 6.0 M KOH solution at 60 °C for WE, it only requires 1.90 V to reach 1000 mA cm−2 and shows excellent stability for 43 h, exhibiting the potential for actual application. The good performance can be assigned to N-doped graphene-decorated NiCo alloy and mesoporous NiCoMoO nano-sheet, which not only increase the intrinsic activity and expose abundant catalytic activity sites, but also enhance its chemical and mechanical stability. This work thus could provide a promising material for industrial hydrogen production.


2019 ◽  
Vol 578 ◽  
pp. 136-148 ◽  
Author(s):  
Stefania Siracusano ◽  
Claudio Oldani ◽  
Maria Assunta Navarra ◽  
Stefano Tonella ◽  
Lucia Mazzapioda ◽  
...  

2020 ◽  
Vol 10 (16) ◽  
pp. 5593-5601 ◽  
Author(s):  
Marco Etzi Coller Pascuzzi ◽  
Alex J. W. Man ◽  
Andrey Goryachev ◽  
Jan P. Hofmann ◽  
Emiel J. M. Hensen

Anodic polarization conducted at high current density, elevated temperature, and high KOH concentration impacted the structure and performance of NiFeOxHy and NiOxHy anodes.


2018 ◽  
Vol 6 (39) ◽  
pp. 19221-19230 ◽  
Author(s):  
Shasha Li ◽  
Suchada Sirisomboonchai ◽  
Akihiro Yoshida ◽  
Xiaowei An ◽  
Xiaogang Hao ◽  
...  

An electrocatalyst composed of CoNi(hydroxide) nanosheets and flower-like CoFe2O4 particles with multiple porous structure is successfully deposited on nickel foam and applied for overall water splitting.


Author(s):  
Liyun Cao ◽  
Yifei Zhang ◽  
Liangliang Feng ◽  
Danyang He ◽  
Qianqian Liu ◽  
...  

A three-dimensional coral-like Zn,O-codoped Ni3S2 nanostructure is grown on nickel foam via a facile solvothermal method, exhibiting excellent electrocatalytic performance at high current density.


2018 ◽  
Vol 8 (16) ◽  
pp. 4151-4158 ◽  
Author(s):  
Leiming Tao ◽  
Man Li ◽  
Shaohang Wu ◽  
Qinglong Wang ◽  
Xin Xiao ◽  
...  

Efficient and low-cost sea coral-like NiCo2O4@(Ni, Co)OOH heterojunction catalysts meet the high current density requirements for industrial water electrolysis applications.


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