Surface decoration of diatomite by Ni/NiO nanoparticles as hybrid composite of enhanced adsorption properties for malachite green dye and hexavalent chromium

Author(s):  
Mostafa R. Abukhadra ◽  
Mohamed Adel Sayed ◽  
Abdelrahman M. Rabie ◽  
Sayed A. Ahmed
Author(s):  
Hesham H. El-Feky ◽  
Reham N. Nassar ◽  
Alaa S. Amin ◽  
Mostafa Y. Nassar

Nickel oxide nanostructures were synthesized via a sol-gel combustion method using glucose, glycine and tartaric acid fuels. The effect of the fuel type on the formed nanostructures was studied. The as-prepared products were characterized by means of FE-SEM, HR-TEM, XRD, and FT-IR analyses. The results exhibited that the used fuels gave NiO products with different morphologies, and the glucose fuel produced pure NiO nanoparticles with the smallest crystallite size (ca. 8.2 nm). The adsorption properties of the NiO products for the removal of malachite green dye (MG) was examined. Using a batch method, various parameters affecting the adsorption properties were studied. The results revealed that NiO nanostructure generated from the glucose fuel had the highest adsorption capacity


2020 ◽  
Vol 10 (6) ◽  
pp. 849-859
Author(s):  
Radwa A. El-Salamony ◽  
Abeer A. Emam ◽  
Nagwa A. Badawy ◽  
Sara F. El-Morsi

Objective: ZnO nanoparticles were synthesized using wet impregnation method, and activated carbon from rice straw (RS) prepared through chemical route. Methods: The nano-composites ZnO-AC series were prepared with different ZnO:AC ratio of 10, 20, 50, and 70% to optimize the zinc oxide nanoparticles used. The obtained composites were characterized by FE-SEM, XRD, SBET, and optical techniques then used for the photo-degradation of Malachite green dye (MG) under visible light. Results: It was found that 10ZnO-AC exhibited excellent visible light photo-catalytic performance. The ·OH radicals’ formation is matching with photo-activity of the prepared composites. The photo-degradation efficiency of MG increased from 63% to 93%, when the 10ZnO-AC photocatalyst amount was increased from 0.5 to 6 g/L. Conclusion: The GC-MS technique was used to analyze the intermediates formed; up to 15 kinds of chemicals were identified as the degradation products.


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