Influence of molar mass of partially hydrolyzed polyacrylamide on the treatment of produced water from enhanced oil recovery

Author(s):  
Allan S. Santos ◽  
Anny M.T. Marques ◽  
Luiz C.M. Palermo ◽  
Claudia R.E. Mansur
2020 ◽  
Vol 143 (6) ◽  
Author(s):  
Pan-Sang Kang ◽  
Jong-Se Lim ◽  
Chun Huh

Abstract The viscosity of injection fluid is a critical parameter that should be considered for the design and evaluation of polymer flood, which is an effective and popular technique for enhanced oil recovery (EOR). It is known that the shear-thinning behavior of EOR polymer solutions is affected by temperature. In this study, temperature dependence (25–70 °C) of the viscosity of a partially hydrolyzed polyacrylamide solution, the most widely used EOR polymer for oil field applications, was measured under varying conditions of the polymer solution (polymer concentration: 500–3000 ppm, NaCl salinity: 1000–10,000 ppm). Under all conditions of the polymer solution, it was observed that the viscosity decreases with increasing temperature. The degree of temperature dependence, however, varies with the conditions of the polymer solution. Martin model and Lee correlations were used to estimate the dependence of the viscosity of the polymer solution on the polymer concentration and salinity. In this study, we proposed a new empirical model to better elucidate the temperature dependence of intrinsic viscosity. Analysis of the measured viscosities shows that the accuracy of the proposed temperature model is higher than that of the existing temperature model.


2021 ◽  
Vol 874 ◽  
pp. 45-49
Author(s):  
Ihsan Arifin ◽  
Grandprix Thomryes Marth Kadja ◽  
Cynthia L. Radiman

Enhanced Oil Recovery (EOR) is a promising technology for increasing crude oil production, especially from old wells. Polymer flooding is one of the techniques used in EOR in which the water-soluble polymer is added to increase the viscosity of the injected fluid. However, this technique has not been implemented in Indonesia due to the unavailability of locally-synthesized polymers. Therefore, this research aims to synthesize polyacrylamides and their partially-hydrolyzed derivatives and to study the possibility of their utilization for the EOR application. Various polymerization conditions using potassium persulfate (KPS) as initiators have been realized and the resulting polymers were characterized using FTIR spectroscopy and rheology measurement. It was found that higher monomer concentration resulted in higher viscosity-average molecular weight of polyacrylamide. Further study revealed that the hydrolysis of polyacrylamide by alkaline solution significantly increased the viscosity of 1000 ppm solution from 1.5 to 145.40 cP at room temperature, which is comparable to one of the commercial products. These results showed that the simple synthesis and hydrolysis method could be effectively used to produce water-soluble polymers for the EOR application.


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