Stability Analysis of GMZ Bentonite Colloids: Aggregation Mechanism Transition and the Edge Effect in Strongly Alkaline Conditions

Author(s):  
Dongfan Xian ◽  
Wanqiang Zhou ◽  
Duoqiang Pan ◽  
Liang Du ◽  
Mingkai Chang ◽  
...  
Author(s):  
M. F. Stevens ◽  
P. S. Follansbee

The strain rate sensitivity of a variety of materials is known to increase rapidly at strain rates exceeding ∼103 sec-1. This transition has most often in the past been attributed to a transition from thermally activated guide to viscous drag control. An important condition for imposition of dislocation drag effects is that the applied stress, σ, must be on the order of or greater than the threshold stress, which is the flow stress at OK. From Fig. 1, it can be seen for OFE Cu that the ratio of the applied stress to threshold stress remains constant even at strain rates as high as 104 sec-1 suggesting that there is not a mechanism transition but that the intrinsic strength is increasing, since the threshold strength is a mechanical measure of intrinsic strength. These measurements were made at constant strain levels of 0.2, wnich is not a guarantee of constant microstructure. The increase in threshold stress at higher strain rates is a strong indication that the microstructural evolution is a function of strain rate and that the dependence becomes stronger at high strain rates.


2020 ◽  
Vol 8 (44) ◽  
pp. 23323-23329
Author(s):  
Jing Hu ◽  
Siwei Li ◽  
Yuzhi Li ◽  
Jing Wang ◽  
Yunchen Du ◽  
...  

Crystalline–amorphous Ni–Ni(OH)2 core–shell assembled nanosheets exhibit outstanding electrocatalytic activity and stability for hydrogen evolution under alkaline conditions.


2016 ◽  
Vol 44 (3) ◽  
pp. 461-474 ◽  
Author(s):  
J.B. Wehr ◽  
P.M. Kopittke ◽  
S.A. Dalzell ◽  
N.W. Menzies

1974 ◽  
Vol 76 (4) ◽  
pp. 789-800 ◽  
Author(s):  
Samuel F. Sisenwine ◽  
Ann L. Liu ◽  
Hazel B. Kimmel ◽  
Hans W. Ruelius

ABSTRACT The identification of 1β-hydroxynorgestrel among the urinary metabolites of dl-norgestrel and the facile transformation of this compound under mild alkaline conditions to a potentially oestrogenic phenol provide an experimental basis for the conclusion advanced by others that the oestrogens present in the urine of subjects treated with synthetic progestens are artifacts formed during analytical work-up. A method has been devised which eliminates 1-hydroxylated metabolites as potential sources of phenolic artifacts. This method is based on the reduction by NaBH4 of the 1-hydroxy-4-en-3-one grouping in the A ring thereby excluding the possibility of aromatization during later fractionation on a basic ion exchange resin that separates neutral from phenolic metabolites. In the urines of women treated with 14C-dl-nogestrel, only 0.17–0.27% of the dose is found to have phenolic properties when this method is used. Two of the phenolic metabolites, 18-homoethynyloestradiol and 16β-hydroxy-18-homoethynyloestradiol, are present in amounts smaller than 0.01 % of the dose. Without the reduction steps the percentages are noticeably higher, indicating artifact formation under alkaline conditions. Similar results were obtained with urines from African Green Monkeys (Cercopithecus Aethiops) that had been dosed with 14C-dl-norgestrel. Radiolabelled 18-homoethynyloestradiol and 16β-hydroxy-18-homoethynyloestradiol were isolated from monkey urine and their identity confirmed by gas chromatography-mass spectrometry.


Sign in / Sign up

Export Citation Format

Share Document